Poly(ester-carbonates) containing poly(lactic-glycolic acid) and poly(ethylene glycol) segments

被引:0
|
作者
Penco, M
Becattini, M
Ferruti, P
DAntone, S
Deghenghi, R
机构
[1] UNIV BRESCIA,DIPARTIMENTO CHIM & FIS MAT,I-25133 BRESCIA,ITALY
[2] DIPARTIMENTO CHIM & CHIM IND,I-56100 PISA,ITALY
[3] EUROPEPTIDES GEIE,F-951009 ARGENTEUIL,FRANCE
关键词
poly(lactic-glycolic acid); block copolymers; biodegradable polymers; poly(ester-carbonates); poly(ethylene glycol);
D O I
暂无
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The aim of the present paper is to report on the synthesis, characterization and structure-property relationships of a novel family of highly hydrophilic segmented copoly(ester-ether-carbonates). The synthetic process is based on a chain-extension reaction involving low molecular weight poly(lactic-glycolic acid) copolymers, obtained by thermal polycondensation, and the alpha, omega-bis(chloroformates) of poly(ethylene glycol)s. The resulting products have been characterized in terms of molecular weight, thermal properties and water absorption.
引用
收藏
页码:536 / 542
页数:7
相关论文
共 50 条
  • [1] Degradation behaviour of block copolymers containing poly(lactic-glycolic acid) and poly(ethylene glycol) segments
    Penco, M
    Marcioni, S
    Ferruti, P
    DAntone, S
    Deghenghi, R
    BIOMATERIALS, 1996, 17 (16) : 1583 - 1590
  • [2] NEW HIGH-MOLECULAR-WEIGHT POLY(ESTER-CARBONATES) BY CHAIN EXTENSION OF POLY(LACTIC-GLYCOLIC ACID)
    PENCO, M
    RANUCCI, E
    BIGNOTTI, F
    FERRUTI, P
    DEGHENGHI, R
    MACROMOLECULAR RAPID COMMUNICATIONS, 1994, 15 (09) : 683 - 690
  • [3] Thermal degradation of two classes of block copolymers based on poly(lactic-glycolic acid) and poly(ε-caprolactone) or poly(ethylene glycol)
    Bignotti, F
    Penco, M
    Sartore, L
    D'Antone, S
    D'Amore, A
    Spagnoli, G
    MACROMOLECULAR SYMPOSIA, 2002, 180 : 257 - 266
  • [4] Thermogravimetric investigation of two classes of block copolymers based on poly(lactic-glycolic acid) and poly(ε-caprolactone) or poly(ethylene glycol)
    D'Antone, S
    Bignotti, F
    Sartore, L
    D'Amore, A
    Spagnoli, G
    Penco, M
    POLYMER DEGRADATION AND STABILITY, 2001, 74 (01) : 119 - 124
  • [5] New poly(ester-carbonate) multi-block copolymers based on poly(lactic-glycolic acid) and poly(ε-caprolactone) segments
    Penco, M
    Donetti, R
    Mendichi, R
    Ferruti, P
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1998, 199 (08) : 1737 - 1745
  • [6] SYNTHESIS AND PROPERTIES OF NOVEL BLOCK-COPOLYMERS CONTAINING POLY(LACTIC-GLYCOLIC ACID) AND POLY(ETHYLENEGLYCOL) SEGMENTS
    FERRUTI, P
    PENCE, M
    DADDATO, P
    RANUCCI, E
    DEGHENGHI, R
    BIOMATERIALS, 1995, 16 (18) : 1423 - 1428
  • [7] Modification of Poly(lactic/glycolic acid) Surface by Chemical Attachment of Poly(ethylene glycol)
    Kiss, E.
    Kutnyanszky, E.
    Bertoti, I.
    LANGMUIR, 2010, 26 (03) : 1440 - 1444
  • [8] Thermogravimetric analysis of poly(ester-carbonates) and poly(ester-thiocarbonates)
    Tagle, LH
    Diaz, FR
    INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS, 1995, 28 (1-4) : 187 - 197
  • [9] Miscibility and biodegradability of poly(lactic acid) poly(ethylene oxide) and poly(lactic acid) poly(ethylene glycol) blends
    Yue, CL
    Kumar, RA
    Gross, RA
    McCarthy, SP
    ANTEC '96: PLASTICS - RACING INTO THE FUTURE, VOLS I-III: VOL I: PROCESSING; VOL II: MATERIALS; VOL III: SPACIAL AREAS, 1996, 42 : 1611 - 1615
  • [10] Properties of poly(ethylene glycol)-grafted poly(lactic acid) plasticized with poly(ethylene glycol)
    Choi, Kyung-Man
    Lim, Sung-Wook
    Choi, Myeon-Cheon
    Han, Dong-Hun
    Ha, Chang-Sik
    MACROMOLECULAR RESEARCH, 2014, 22 (12) : 1312 - 1319