Oligomerization of isobutene over solid acid catalysts

被引：61
|
作者：
Hauge, K
Bergene, E
Chen, D
Fredriksen, GR
Holmen, A [1 ]
机构：
[1] Norwegian Univ Sci & Technol, NTNU, Dept Chem Engn, N-7491 Trondheim, Norway
[2] SINTEF, Mat & Chem, N-7465 Trondheim, Norway
[3] STATOIL, Res Ctr, N-7005 Trondheim, Norway
来源：
CATALYSIS TODAY | 2005年 / 100卷 / 3-4期
关键词：
oligomerization; dimerization; isobutene; resin; zeolite; stability;
D O I：
10.1016/j.cattod.2004.08.017
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Oligomerization of isobutene has been carried out in the liquid phase at mild conditions using n-butane as a diluent. The reaction was studied at low temperatures (30-70 degrees C) and at pressures high enough to ensure that the reaction takes place in the liquid phase. A number of different resins and zeolites were evaluated as catalysts for the dimerization. The best performance was obtained with Amberlyst 15 whereas the zeolites (H-ZSM5, H-Mordenite, beta and Y) all showed very rapid deactivation. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：463 / 466
页数：4
相关论文
共 50 条
  • [41] ALKYLATION OF ISOBUTANE WITH BUTENES OVER SOLID ACID CATALYSTS
    GUO, CX
    LIAO, SJ
    QIAN, ZH
    TANABE, K
    APPLIED CATALYSIS A-GENERAL, 1994, 107 (02) : 239 - 248
  • [42] Selective transalkylation of biphenyl over solid acid catalysts
    R. and D. Laboratories, Nippon Steel Chemical Co., Ltd., Nakabaru, Sakinohama, Tobata-ku, Kitakyushu-shi 804, Japan
    Appl Catal A Gen, 1 (87-91):
  • [43] REACTIONS OF KETOXIMES AND ALDOXIMES OVER SOLID ACID CATALYSTS
    CURTIN, T
    HODNETT, BK
    HETEROGENEOUS CATALYSIS AND FINE CHEMICALS III, 1993, 78 : 535 - 542
  • [44] Dehydration of ethanol into ethylene over solid acid catalysts
    Takahara, I
    Saito, M
    Inaba, M
    Murata, K
    CATALYSIS LETTERS, 2005, 105 (3-4) : 249 - 252
  • [45] REARRANGEMENT OF AROMATIC ACETALS OVER SOLID ACID CATALYSTS
    XAVIER, N
    ARULRAJ, SJ
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1985, 24 (05): : 519 - 522
  • [46] Hydrolysis of Oligosaccharides Over Solid Acid Catalysts: A Review
    Vilcocq, Lea
    Castilho, Paula C.
    Carvalheiro, Florbela
    Duarte, Luis C.
    CHEMSUSCHEM, 2014, 7 (04) : 1010 - 1019
  • [47] Selective transalkylation of biphenyl over solid acid catalysts
    Takeuchi, G
    Shimoura, Y
    Hara, T
    APPLIED CATALYSIS A-GENERAL, 1996, 137 (01) : 87 - 91
  • [48] Liquefaction of polyethylene wax over solid acid catalysts
    Shim, JS
    You, YS
    Kim, JH
    Seo, G
    SCIENCE AND TECHNOLOGY IN CATALYSIS 1998, 1999, 121 : 465 - 468
  • [49] Isopropylation of naphthalene over solid acid catalysts.
    Toba, M
    Katayama, A
    Takeuchi, G
    Mizukami, F
    Niwa, S
    Mitamura, S
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 215 : U130 - U130
  • [50] Recyclable and reusable solid Lewis acid catalysts based on crystalline polyolefins; Oligomerization of isobutylene
    Chung, TC
    Kumar, A
    Ding, RD
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 211 : 402 - POLY
12345