(2,2′-Bipyridine-κ2N,N′)chlorido(1,4,7-trithiacyclononane-κ3S,S′,S")ruthenium(II) nitrate monohydrate

被引：1
|
作者：
Fernandes, Jose A. [1 ]
Almeida Paz, Filipe A. [1 ]
Mota, Maria Joao P. [1 ]
Braga, Susana S. [1 ]
Santos, Teresa M. [1 ]
机构：
[1] Univ Aveiro, CICECO, Dept Chem, P-3810193 Aveiro, Portugal
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
STRUCTURAL-CHARACTERIZATION; CYCLODEXTRINS; COMPLEXES;
D O I：
10.1107/S1600536810046556
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [RuCl(C10H8N2)(C6H12S3)]NO3 center dot H2O or [RuCl(bpy)([9]aneS(3))]NO3 center dot H2O, ([9]aneS(3) is 1,4,7-trithiacyclononane and bpy is 2,2'-bipyridine), the Ru-II cation has a slightly distorted octahedral environment composed of three facially coordinated S atoms from ([9]aneS(3)), two N atoms from bpy and a chloride anion. The nitrate counter-ion and the water molecule of crystallization are engaged in O-H center dot center dot center dot O hydrogen-bonding interactions, leading to a supramolecular chain running parallel to the c axis.
引用
收藏
页码：M1575 / U868
页数：12
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