Single protonation labilises but double protonation inhibits substitution of [Fe4S4Cl4]2-

被引：19
|
作者：
Henderson, RA [1 ]
Oglieve, KE [1 ]
机构：
[1] John Innes Ctr Plant Sci Res, Nitrogen Fixat Lab, Norwich NR4 7UH, Norfolk, England
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 11期
关键词：
D O I：
10.1039/a802303d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Successive protonation of [Fe4S4(SPh)(4)](2-) progressively labilises the cluster towards substitution of the thiolate ligands, whereas single protonation of [Fe4S4Cl4](2-) catalyses, but diprotonation inhibits, substitution of the chloro-ligands.
引用
收藏
页码：1731 / 1733
页数：3
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