Single protonation labilises but double protonation inhibits substitution of [Fe4S4Cl4]2-

被引：19

作者：

Henderson, RA ^{[1
]}

Oglieve, KE ^{[1
]}

机构：

[1] John Innes Ctr Plant Sci Res, Nitrogen Fixat Lab, Norwich NR4 7UH, Norfolk, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 11期

关键词：

D O I：

10.1039/a802303d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Successive protonation of [Fe4S4(SPh)(4)](2-) progressively labilises the cluster towards substitution of the thiolate ligands, whereas single protonation of [Fe4S4Cl4](2-) catalyses, but diprotonation inhibits, substitution of the chloro-ligands.

引用

页码：1731 / 1733

页数：3

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