Solvent-solute interactions in ionic liquids

被引：713
|
作者：
Crowhurst, L [1 ]
Mawdsley, PR [1 ]
Perez-Arlandis, JM [1 ]
Salter, PA [1 ]
Welton, T [1 ]
机构：
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2003年 / 5卷 / 13期
关键词：
D O I：
10.1039/b303095d
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A range of ionic liquids has been investigated using the Kamlet - Taft parameters alpha, beta, and pi*. It was found that pi* is high for all of the ionic liquids studied and varies with both anion and cation, a is generally moderate and depends mainly on the cation, beta is also moderate and depends mainly on the anion. Comparison is made with other polarity measurements in ionic liquids.
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页码：2790 / 2794
页数：5
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