Solvent-solute interactions in ionic liquids

被引：712

作者：

Crowhurst, L ^{[1
]}

Mawdsley, PR ^{[1
]}

Perez-Arlandis, JM ^{[1
]}

Salter, PA ^{[1
]}

Welton, T ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2003年 / 5卷 / 13期

关键词：

D O I：

10.1039/b303095d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A range of ionic liquids has been investigated using the Kamlet - Taft parameters alpha, beta, and pi*. It was found that pi* is high for all of the ionic liquids studied and varies with both anion and cation, a is generally moderate and depends mainly on the cation, beta is also moderate and depends mainly on the anion. Comparison is made with other polarity measurements in ionic liquids.

引用

页码：2790 / 2794

页数：5

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