Differential-pulse adsorptive stripping voltammetric determination of the antibacterial lomefloxacin

被引：21
|
作者：
Vílchez, JL [1 ]
Araujo, L [1 ]
Prieto, A [1 ]
Navalón, A [1 ]
机构：
[1] Univ Granada, Fac Sci, Dept Analyt Chem, E-18071 Granada, Spain
来源：
JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS | 2001年 / 26卷 / 01期
关键词：
differential-pulse voltammetry; adsorptive stripping; antibacterials; lomefloxacin;
D O I：
10.1016/S0731-7085(01)00391-0
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A differential-pulse adsorptive stripping voltammetric method for the determination of trace amounts of the antibacterial lomefloxacin is proposed, By using an accumulation potential of -0.30 V and a 2 min accumulation time, the linear concentration range of application was 1.0-10.0 ng ml(-1) of lomefloxacin. with a relative standard deviation of 3.8% (for a level of 5.0 ng ml(-1)) and a detection limit of 0.3 ng ml(-1). The method was applied to determination of lomefloxacin in human urine and serum samples. It was validated using HPLC as a reference method. Recovery levels of the method reached 100% in all cases. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：23 / 29
页数：7
相关论文
共 50 条
  • [1] Determination of the antibacterial enrofloxacin by differential-pulse adsorptive stripping voltammetry
    Navalón, A
    Blanc, R
    Reyes, L
    Navas, N
    Vílchez, JL
    [J]. ANALYTICA CHIMICA ACTA, 2002, 454 (01) : 83 - 91
  • [2] Determination of the antibacterial trovafloxacin by differential-pulse adsorptive stripping voltammetry
    Vílchez, JL
    Taoufiki, J
    Araujo, L
    Navalón, A
    [J]. JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 2003, 31 (03) : 465 - 471
  • [3] DIFFERENTIAL-PULSE POLAROGRAPHY AND ADSORPTIVE STRIPPING VOLTAMMETRIC DETERMINATION OF URIC-ACID
    GANDOUR, MA
    ENSAFABOULKASIM
    AMRALLAH, AH
    FARGHALY, OA
    [J]. JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1992, 69 (12) : 813 - 818
  • [4] DIFFERENTIAL-PULSE ADSORPTIVE STRIPPING VOLTAMMETRIC DETERMINATION OF SODIUM CROMOGLYCATE AT A HANGING MERCURY DROP ELECTRODE
    MOREIRA, JC
    FOSTER, SE
    RODRIGUES, JA
    FOGG, AG
    [J]. ANALYST, 1992, 117 (06) : 989 - 991
  • [5] DIFFERENTIAL-PULSE ADSORPTIVE STRIPPING VOLTAMMETRIC DETERMINATION OF NICKEL AND COBALT IN HIGH-PURITY ALUMINUM
    PALRECHA, MM
    [J]. FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1995, 351 (08): : 800 - 801
  • [6] ADSORPTIVE DIFFERENTIAL-PULSE VOLTAMMETRIC DETERMINATION OF TRACE AMOUNTS OF RUTHENIUM
    PALANIAPPAN, R
    KUMAR, TA
    [J]. ANALYST, 1993, 118 (03) : 293 - 296
  • [7] DIFFERENTIAL-PULSE ADSORPTIVE STRIPPING VOLTAMMETRY OF CHLORHEXIDINE
    GRATTERI, P
    PINZAUTI, S
    LAPORTA, E
    PAPESCHI, G
    CAVRINI, V
    SANTONI, G
    [J]. ANALYST, 1991, 116 (07) : 723 - 725
  • [8] Differential pulse adsorptive stripping voltammetric determination of zafirlukast in pharmaceutical formulations
    Süslü, I
    Altinöz, S
    [J]. ANALYTICAL LETTERS, 2005, 38 (10) : 1625 - 1639
  • [9] DETERMINATION OF CEFTRIAXONE IN BIOLOGICAL-MATERIAL BY DIFFERENTIAL-PULSE ADSORPTIVE STRIPPING VOLTAMMETRY
    ALTINOZ, S
    TEMIZER, A
    BEKSAC, S
    [J]. ANALYST, 1990, 115 (06) : 873 - 874
  • [10] ADSORPTIVE STRIPPING VOLTAMMETRIC BEHAVIOR OF SULFAQUINOXALINE USING DIFFERENTIAL-PULSE AND SQUARE-WAVE TECHNIQUES
    BERZAS, JJ
    RODRIGUEZ, J
    LEMUS, JM
    CASTANEDA, G
    [J]. ANALYTICA CHIMICA ACTA, 1993, 273 (1-2) : 369 - 375
12345