Statistical mechanics of helical wormlike chain model

被引:9
|
作者
Liu, Ya [1 ]
Perez, Toni [1 ]
Li, Wei [1 ]
Gunton, J. D. [1 ]
Green, Amanda [2 ]
机构
[1] Lehigh Univ, Dept Phys, Bethlehem, PA 18015 USA
[2] Bucknell Univ, Dept Phys, Lewisburg, PA 17837 USA
来源
JOURNAL OF CHEMICAL PHYSICS | 2011年 / 134卷 / 06期
基金
美国国家科学基金会;
关键词
TWISTING ELASTICITY; DYNAMICS; DNA; FILAMENTS; POLYMERS;
D O I
10.1063/1.3548885
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We investigate the statistical mechanics of polymers with bending and torsional elasticity described by the helical wormlike model. Noticing that the energy function is factorizable, we provide a numerical method to solve the model using a transfer matrix formulation. The tangent-tangent and binormal-binormal correlation functions have been calculated and displayed rich profiles which are sensitive to the combination of the temperature and the equilibrium torsion. Their behaviors indicate that there is no finite temperature Lifshitz point between the disordered and helical phases. The asymptotic behavior at low temperature has been investigated theoretically and the predictions fit the numerical results very well. Our analysis could be used to understand the statics of dsDNA and other chiral polymers. (C) 2011 American Institute of Physics. [doi:10.1063/1.3548885]
引用
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页数:6
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