Co(II)-Catalyzed Regioselective Cross-Dehydrogenative Coupling of Aryl C-H Bonds with Carboxylic Acids

被引：78
|
作者：
Lan, Jianyong [1 ]
Xie, Haisheng [1 ]
Lu, Xiaoxia [2 ]
Deng, Yuanfu [1 ]
Jiang, Huanfeng [1 ]
Zeng, Wei [1 ]
机构：
[1] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510641, Guangdong, Peoples R China
[2] Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Sichuan, Peoples R China
来源：
ORGANIC LETTERS | 2017年 / 19卷 / 16期
关键词：
CARBON-HYDROGEN BONDS; PHOSPHORAMIDATE PROTIDES; AMINATION; FUNCTIONALIZATION; SUBSTITUTION; ALKYLAMINES; ANHYDRIDES; ARYLATION; OXIDATION; CLEAVAGE;
D O I：
10.1021/acs.orglett.7b01942
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A cobalt(II)-catalyzed regioselective aryl C-H bond oxygenation between arenes and aryl or aliphatic carboxylic acids under bidendate-chelation assistance is developed. This method provides an efficient approach to acyoxy-substituted arenes with a broad range of functional group tolerance. Furthermore, this reaction system could be further applied to the preparation of polyfunctional naphthylenes
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页码：4279 / 4282
页数：4
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