A tri-functional metal-organic framework heterogeneous catalyst for efficient conversion of CO2 under mild and co-catalyst free conditions

被引：44

作者：

Ma, Dingxuan ^{[1
]}

Zhang, Yaowen ^{[1
]}

Jiao, Shaoshao ^{[1
]}

Li, Jixin ^{[2
]}

Liu, Kang ^{[1
]}

Shi, Zhan ^{[2
]}

机构：

[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Minist Educ, Lab Ecochem Engn, Qingdao 266042, Shandong, Peoples R China

[2] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 95期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE; CYCLIC CARBONATES; CHEMICAL FIXATION; MOF; CAPTURE; ADSORPTION; EPOXIDES;

D O I：

10.1039/c9cc08236k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we developed a tri-functional MOF heterogeneous catalyst, MIL-IMAc-Br-, by a post-synthesis modification method for the first time. Due to the synergistic role of three functional sites, including Lewis acid sites, Bronsted acid sites and Br- anion sites, MIL-IMAc-Br- displayed an efficient catalytic performance for the cycloaddition reaction of CO2 and epoxides to form cyclic carbonates under mild and co-catalyst free conditions.

引用

页码：14347 / 14350

页数：4

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