Ordered mesoporous materials as solid supports for rhodium-diphosphine catalysts with remarkable hydroformylation activity

被引：37
|
作者：
Marras, Fabrizio [1 ]
Wang, Jia [2 ]
Coppens, Marc-Olivier [2 ,3 ]
Reek, Joost N. H. [1 ]
机构：
[1] Univ Amsterdam, vant Hoff Inst Mol Sci, Supramol & Homogeneous Catalysis Grp, NL-1018 WV Amsterdam, Netherlands
[2] Delft Univ Technol, NL-2628 BL Delft, Netherlands
[3] Rensselaer Polytech Inst, Dept Chem & Biol Engn, Troy, NY 12180 USA
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 35期
基金：
美国国家科学基金会;
关键词：
FUNCTIONALIZED MONOLAYERS; IMINE HYDROGENATION; MOLECULAR-SIEVES; SILICA; COPOLYMER; TRIBLOCK;
D O I：
10.1039/c0cc00924e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A rhodium-diphosphine complex based on Xantphos-type ligands was anchored on mesoporous silica SBA-15, and the material showed remarkably high catalytic activity in the hydroformylation of 1-octene, even exceeding its homogeneous analogue under certain conditions.
引用
收藏
页码：6587 / 6589
页数：3
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