Bis(2,6-dihydroxybenzoato-κ2O1,O1′)(nitrato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)neodymium(III)

被引：6
|
作者：
Zheng, Junjia [1 ]
Jin, Hongxiao [1 ]
Ge, Hongliang [1 ]
机构：
[1] China Jiliang Univ, Coll Mat Sci & Engn, Hangzhou 310018, Zhejiang, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
D O I：
10.1107/S1600536810042583
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the mononuclear title complex, [Nd(C7H5O4)(2)(NO3)-(C12H8N2)(2)], the Nd-III atom is in a distorted bicapped square-antiprismatic geometry formed by four N atoms from two chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2,6-dihydroxybenzoate (DHB) ligands and two O atoms from a nitrate anion. pi-pi stacking interactions between the phen and DHB ligands of adjacent complexes [centroid-centroid distances = 3.520 (6) and 3.798 (6) angstrom] stabilize the crystal structure. Intramolecular O-H center dot center dot center dot O hydrogen bonds are observed in the DHB ligands.
引用
收藏
页码：M1469 / U1238
页数：15
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