Synthesis and properties of poly(N-phenylphenyleneamine)s

被引:4
|
作者
Grigalevicius, S [1 ]
Buika, G [1 ]
Grazulevicius, JV [1 ]
机构
[1] Kaunas Univ Technol, Dept Organ Technol, LT-3028 Kaunas, Lithuania
关键词
poly(N-phenylphenyleneamine); amorphous material; pi-electron system; ionization potential;
D O I
10.1016/S0254-0584(03)00182-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Poly(N-phenylphenyleneamine)s have been synthesized by a modified Ullmann condensation. The number average molecular weights of the oligomers synthesized were in the range of 1350-1700 with a molecular weight distribution of 1.6. The oligomers are thermally stable. Their glass transition temperatures range from 166 to 182 degreesC as characterized by differential scanning calorimetry. The electron photoemission spectra of the oligomers have been recorded and the ionization potentials of 5.2-5.4 eV have been established. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:191 / 194
页数:4
相关论文
共 50 条
  • [41] Synthesis and properties of poly(arylene ether pyrazole)s
    Srinivasan, KR
    Bass, RG
    Smith, JG
    HIGH PERFORMANCE POLYMERS, 1996, 8 (03) : 381 - 393
  • [42] SYNTHESIS AND PROPERTIES OF POLY(IMIDE-SULFONATE)S
    CHOI, KY
    CHOI, SK
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1982, 20 (04) : 1107 - 1117
  • [43] Synthesis, thermal and mechanical properties of poly(methylphenylsilmethylene)s
    Ogawa, T
    Murakami, M
    CHEMISTRY OF MATERIALS, 1996, 8 (06) : 1260 - 1267
  • [44] Poly(ionic liquid)s: Synthesis, properties, and application
    Shaplov, A. S.
    Ponkratov, D. O.
    Vygodskii, Y. S.
    POLYMER SCIENCE SERIES B, 2016, 58 (02) : 73 - 142
  • [45] SYNTHESIS AND PROPERTIES OF POLY(ALPHA-FLUOROSTYRENE)S
    KNEBELKAMP, A
    HEITZ, W
    MAKROMOLEKULARE CHEMIE-RAPID COMMUNICATIONS, 1991, 12 (10): : 597 - 606
  • [46] Synthesis and properties of novel poly(amine ether)s
    Chang Guan-Jun
    Xu Zhe
    Lin Run-Xiong
    Luo Xuan
    CHINESE JOURNAL OF CHEMISTRY, 2007, 25 (08) : 1207 - 1211
  • [47] SYNTHESIS AND PROPERTIES OF POLY(ARYLENE ETHER BENZIMIDAZOLE)S
    HERGENROTHER, PM
    SMITH, JG
    CONNELL, JW
    POLYMER, 1993, 34 (04) : 856 - 865
  • [48] Synthesis, Thermal and Mechanical Properties of Poly(methylphenylsilmethylene)s
    Ogawa, T.
    Murakami, M.
    Chemistry of Materials, 8 (06):
  • [49] SYNTHESIS AND PROPERTIES OF POLY(ARYLENE ETHER BENZIMIDAZOLE)S
    SMITH, JG
    CONNELL, JW
    HERGENROTHER, PM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 202 : 25 - POLY
  • [50] Poly(ionic liquid)s: Synthesis, properties, and application
    A. S. Shaplov
    D. O. Ponkratov
    Y. S. Vygodskii
    Polymer Science Series B, 2016, 58 : 73 - 142