Synthesis and properties of poly(N-phenylphenyleneamine)s

被引：4
|
作者：
Grigalevicius, S [1 ]
Buika, G [1 ]
Grazulevicius, JV [1 ]
机构：
[1] Kaunas Univ Technol, Dept Organ Technol, LT-3028 Kaunas, Lithuania
来源：
MATERIALS CHEMISTRY AND PHYSICS | 2003年 / 81卷 / 01期
关键词：
poly(N-phenylphenyleneamine); amorphous material; pi-electron system; ionization potential;
D O I：
10.1016/S0254-0584(03)00182-2
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Poly(N-phenylphenyleneamine)s have been synthesized by a modified Ullmann condensation. The number average molecular weights of the oligomers synthesized were in the range of 1350-1700 with a molecular weight distribution of 1.6. The oligomers are thermally stable. Their glass transition temperatures range from 166 to 182 degreesC as characterized by differential scanning calorimetry. The electron photoemission spectra of the oligomers have been recorded and the ionization potentials of 5.2-5.4 eV have been established. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：191 / 194
页数：4
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