A nonlinear optical active polymer film based on Pd(II) dithione/dithiolate second-order NLO chromophores

被引：7
|
作者：
Espa, D. [1 ]
Pilia, L. [1 ,2 ]
Marchio, L. [3 ]
Artizzu, F. [1 ]
Di Carlo, G. [4 ]
Marinotto, D. [4 ]
Serpe, A. [1 ]
Tessore, F. [4 ]
Deplano, P. [1 ,5 ]
机构：
[1] Univ Cagliari, Unita Ric INSTM, Diparamento Sci Chim & Geol, SS 554 Bivio Sestu, I-109042 Monserrato Cagilari, Italy
[2] Univ Cagliari, Dipartimento Ingn Meccan Chim & Mat, Via Marengo 2, I-109123 Cagliari, Italy
[3] Univ Parma, Dipartimento Chim, Parco Area Sci 17A, I-143100 Parma, Italy
[4] Univ Milan, Dipartimento Chim, Unita Ric INSTM, Via C Golgi 19, I-20133 Milan, Italy
[5] Univ Cagliari, Dipartimento Fis, SS 554 Bivio Sestu, I-109042 Monserralo Cagliari, Italy
来源：
DALTON TRANSACTIONS | 2016年 / 45卷 / 43期
关键词：
2ND-HARMONIC GENERATION; MOLECULAR HYPERPOLARIZABILITIES; RUTHENIUM COMPLEXES; POLING DYNAMICS; ACCEPTOR; PD; NI; COORDINATION; DESIGN; LIGAND;
D O I：
10.1039/c6dt02911f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A film of [Pd(R(2)pipdt)(dmit)] (1), where R2pipdt = 1,4-didodecyl-piperazine-2,3-dithione (acceptor) and dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate (donor) incorporated into a polymethylmethacrylate (PMMA) matrix, showing a good second-harmonic generation, has been prepared for the first time in the class of dithione-dithiolate 2nd order NLO-chromophores. Moreover full characterization of 1, including molecular second-order NLO properties in solution, is reported.
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页码：17431 / 17438
页数：8
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