A nonlinear optical active polymer film based on Pd(II) dithione/dithiolate second-order NLO chromophores

被引：7
|
作者：
Espa, D. [1 ]
Pilia, L. [1 ,2 ]
Marchio, L. [3 ]
Artizzu, F. [1 ]
Di Carlo, G. [4 ]
Marinotto, D. [4 ]
Serpe, A. [1 ]
Tessore, F. [4 ]
Deplano, P. [1 ,5 ]
机构：
[1] Univ Cagliari, Unita Ric INSTM, Diparamento Sci Chim & Geol, SS 554 Bivio Sestu, I-109042 Monserrato Cagilari, Italy
[2] Univ Cagliari, Dipartimento Ingn Meccan Chim & Mat, Via Marengo 2, I-109123 Cagliari, Italy
[3] Univ Parma, Dipartimento Chim, Parco Area Sci 17A, I-143100 Parma, Italy
[4] Univ Milan, Dipartimento Chim, Unita Ric INSTM, Via C Golgi 19, I-20133 Milan, Italy
[5] Univ Cagliari, Dipartimento Fis, SS 554 Bivio Sestu, I-109042 Monserralo Cagliari, Italy
来源：
DALTON TRANSACTIONS | 2016年 / 45卷 / 43期
关键词：
2ND-HARMONIC GENERATION; MOLECULAR HYPERPOLARIZABILITIES; RUTHENIUM COMPLEXES; POLING DYNAMICS; ACCEPTOR; PD; NI; COORDINATION; DESIGN; LIGAND;
D O I：
10.1039/c6dt02911f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A film of [Pd(R(2)pipdt)(dmit)] (1), where R2pipdt = 1,4-didodecyl-piperazine-2,3-dithione (acceptor) and dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate (donor) incorporated into a polymethylmethacrylate (PMMA) matrix, showing a good second-harmonic generation, has been prepared for the first time in the class of dithione-dithiolate 2nd order NLO-chromophores. Moreover full characterization of 1, including molecular second-order NLO properties in solution, is reported.
引用
下载
收藏
页码：17431 / 17438
页数：8
相关论文
共 50 条
  • [1] Second-order nonlinear optical polymers based on benzoxazole chromophores
    Park, K.H.
    Shin, D.-H.
    Jahng, W.S.
    Lee, C.J.
    Kim, N.
    Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics, 1999, 20 (01): : 73 - 86
  • [2] Electrochromic second-order NLO chromophores based on MII (M = Ni, Pd, Pt) complexes with diselenolato-dithione (donor-acceptor) ligands
    Espa, Davide
    Pilia, Luca
    Marchio, Luciano
    Pizzotti, Maddalena
    Robertson, Neil
    Tessore, Francesca
    Mercuri, M. Laura
    Serpe, Angela
    Deplano, Paola
    DALTON TRANSACTIONS, 2012, 41 (39) : 12106 - 12113
  • [3] Second-Order Nonlinear Optical (NLO) Properties of a Multichromophoric System Based on an Ensemble of Four Organic NLO Chromophores Nanoorganized on a Cyclotetrasiloxane Architecture
    Ronchi, Marco
    Pizzotti, Maddalena
    Biroli, Alessio Orbelli
    Righetto, Stefania
    Ugo, Renato
    Mussini, Patrizia
    Cavazzini, Marco
    Lucenti, Elena
    Salsa, Matteo
    Fantucci, Piercarlo
    JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (07): : 2745 - 2760
  • [4] Second-Order Nonlinear Optical Properties of Zwitterionic Chromophores
    Teshome, Ayele
    Asselberghs, Inge
    Clarke, David J.
    Middleton, Ayla P.
    Bhuiyan, M. Delower H.
    Smith, Gerald J.
    Kay, Andrew J.
    Clays, Koen
    ORGANIC PHOTONICS IV, 2010, 7722
  • [5] Tunable Chiral Second-Order Nonlinear Optical Chromophores Based on Helquat Dications
    Buckley, Laura E. R.
    Coe, Benjamin J.
    Rusanova, Daniela
    Joshi, Vishwas D.
    Sanchez, Sergio
    Jirasek, Michael
    Vavra, Jan
    Khobragade, Dushant
    Severa, Lukag
    Cisarova, Ivana
    Saman, David
    Pohl, Radek
    Clays, Koen
    Depotter, Griet
    Brunschwig, Bruce S.
    Teply, Filip
    JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 121 (31): : 5842 - 5855
  • [6] Efficient second-order nonlinear optical chromophores based on dithienothiophene and thienothiophene bridges
    Belen Marco, A.
    Andreu, Raquel
    Franco, Santiago
    Garin, Javier
    Orduna, Jesus
    Villacampa, Belen
    Alicante, Raquel
    TETRAHEDRON, 2013, 69 (19) : 3919 - 3926
  • [7] Influence of thiazole regioisomerism on second-order nonlinear optical chromophores
    Galan, Elena
    Andreu, Raquel
    Garin, Javier
    Mosteo, Laura
    Orduna, Jesus
    Villacampa, Belen
    Diosdado, Beatriz E.
    TETRAHEDRON, 2012, 68 (32) : 6427 - 6437
  • [8] Recent Progress of Organic Second-Order Nonlinear Optical Chromophores
    Li, Qianqian
    Qin, Jingui
    Li, Zhen
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2011, 31 (09) : 1337 - 1349
  • [9] Effect of the electrostatic interactions of chromophores on the macroscopic second-order nonlinear optical properties of the polymer films
    Shi, W
    Fang, CS
    Xu, ZL
    Pan, QW
    Zhao, X
    Gu, QT
    Xu, D
    Yu, JZ
    ACTA PHYSICA SINICA, 2000, 49 (05) : 904 - 910
  • [10] Effect of the electrostatic interactions of chromophores on the macroscopic second-order nonlinear optical properties of the polymer films
    Shi, Wei
    Fang, Changshui
    Xu, Zhiling
    Pan, Qiwei
    Zhao, Xian
    Gu, Qingtian
    Xu, Dong
    Yu, Jinzhong
    Wuli Xuebao/Acta Physica Sinica, 2000, 49 (05): : 904 - 910
12345