Advanced and traditional processing of thermoplastic polyurethane waste

被引:14
|
作者
Calvo-Correas, Tamara [1 ,2 ]
Benitez, Miriam [1 ]
Larraza, Izaskun [1 ]
Ugarte, Lorena [1 ,3 ]
Pena-Rodriguez, Cristina [1 ]
Eceiza, Arantxa [1 ]
机构
[1] Univ Basque Country, Fac Engn Gipuzkoa, Dept Chem & Environm Engn, Mat Technol Res Grp GMT, Plaza Europa 1, Donostia San Sebastian 20018, Spain
[2] Univ Basque Country, Fac Engn Vitoria Gasteiz, Dept Environm Engn, Nieves Cano St 12, Vitoria 01006, Spain
[3] Univ Basque Country, Eibar Sect, Fac Engn Gipuzkoa, Dept Graph Express & Project Management, Otaola Hiribidea 29, Eibar 20600, Spain
关键词
Thermoplastic polyurethane; Mechanical recycling; Mechanical processing; 3D printing; Electrospinning; MECHANICAL-PROPERTIES; DEGRADATION; NANOFIBERS;
D O I
10.1016/j.polymdegradstab.2022.109880
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this work different ways to valorise discarded ear tags made of TPU from livestock sector were studied. This singular residue does not require separation from other plastics like other industrial and urbane wastes, which could contribute to simplify its management. Firstly, mechanical processing was carried out by several cycles of consecutive extrusion and injection processes. The material obtained in each process was characterized using different physical, chemical and mechanical characterization techniques in order to study the degradation as a consequence of processing cycles. Thereafter, suitable filaments for 3D printing were obtained and the effect of infill pattern in the mechanical properties of the printed pieces was investigated. Besides, an electrospun mat constituted by TPU waste microfibers was successfully obtained by electrospinning, and its morphology together with superficial and mechanical properties were characterized. Results showed that these applications were suitable options to valorise TPU waste consisting of discarded ear tags. (C) 2022 The Author(s). Published by Elsevier Ltd.
引用
收藏
页数:9
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