Synthesis and structure of chiral silatranes derived from terpenes

被引：0
|
作者：
Wagner, G [1 ]
Herrmann, R
Pedersen, B
Scherer, W
机构：
[1] Inst Tecnol Quim & Biol, Av Republ EAN,Apt 127, P-2781901 Oeiras, Portugal
[2] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2001年 / 56卷 / 01期
关键词：
silatranes; terpenes; chiral pool;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Starting with the chiral pool compounds (-)-menthone, (-)-limonene, (-)-beta -pinene, and (-)-carvone, new homochiral triethanolamine derivatives were obtained and converted to chiral silatranes. These silatranes were characterized by crystal structure analyses and NMR techniques. Conformational analyses in the solid state and in solution show that the chiral terpene residues determine the direction of the ring puckering of the silatrane moiety.
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收藏
页码：25 / 38
页数：14
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