Cu(II) pentaiodobenzoate complexes: "super heavy carboxylates" featuring strong halogen bonding

被引：15

作者：

Bondarenko, Mikhail A. ^{[1
]}

Abramov, Pavel A. ^{[1
]}

Novikov, Alexander S. ^{[2
]}

Sokolov, Maxim N. ^{[1
]}

Adonin, Sergey A. ^{[1
]}

机构：

[1] Nikolaev Inst Inorgan Chem SB RAS, Lavrentieva St 3, Novosibirsk 630090, Russia

[2] St Petersburg State Univ, Univ Skiy St 26, St Petersburg 198504, Russia

来源：

POLYHEDRON | 2022年 / 214卷

基金：

俄罗斯基础研究基金会;

关键词：

Halogen bonding; Copper; Complexes; Non-covalent interactions; Carboxylates; COORDINATION POLYMERS; MAGNETIC-PROPERTIES; MOLECULAR-COMPLEXES; CRYSTAL-STRUCTURES; METAL-COMPLEXES; SOLID-STATE; LIGANDS; HEXAFLUOROACETYLACETONATE; TRANSITION; STABILIZATION;

D O I：

10.1016/j.poly.2021.115644

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first heteroleptic pentaiodobenzoate (PIBA) metal complexes [Cu(PIBA)(2)L-2] (L = Py (1), 3,5-MePy (2), 2,6-MePy (3)) and [Cu(PIBA)(2)(4-MePy)(DMF)(1.5)(H2O)(0.5)].2DMF (4) were prepared and characterized. In most cases, there are multiple strong halogen bonds and Type I halogen...halogen interactions in their structures; the en-ergies of these contacts were estimated by theoretical methods. Thermal stability of 1-4 was studied by ther-mogravimetric analysis.

引用

页数：6

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