Cu(II) pentaiodobenzoate complexes: "super heavy carboxylates" featuring strong halogen bonding

被引：15

作者：

Bondarenko, Mikhail A. ^{[1
]}

Abramov, Pavel A. ^{[1
]}

Novikov, Alexander S. ^{[2
]}

Sokolov, Maxim N. ^{[1
]}

Adonin, Sergey A. ^{[1
]}

机构：

[1] Nikolaev Inst Inorgan Chem SB RAS, Lavrentieva St 3, Novosibirsk 630090, Russia

[2] St Petersburg State Univ, Univ Skiy St 26, St Petersburg 198504, Russia

来源：

POLYHEDRON | 2022年 / 214卷

基金：

俄罗斯基础研究基金会;

关键词：

Halogen bonding; Copper; Complexes; Non-covalent interactions; Carboxylates; COORDINATION POLYMERS; MAGNETIC-PROPERTIES; MOLECULAR-COMPLEXES; CRYSTAL-STRUCTURES; METAL-COMPLEXES; SOLID-STATE; LIGANDS; HEXAFLUOROACETYLACETONATE; TRANSITION; STABILIZATION;

D O I：

10.1016/j.poly.2021.115644

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first heteroleptic pentaiodobenzoate (PIBA) metal complexes [Cu(PIBA)(2)L-2] (L = Py (1), 3,5-MePy (2), 2,6-MePy (3)) and [Cu(PIBA)(2)(4-MePy)(DMF)(1.5)(H2O)(0.5)].2DMF (4) were prepared and characterized. In most cases, there are multiple strong halogen bonds and Type I halogen...halogen interactions in their structures; the en-ergies of these contacts were estimated by theoretical methods. Thermal stability of 1-4 was studied by ther-mogravimetric analysis.

引用

页数：6

共 50 条

[1] Two Cu(II) complexes involving halogen bonding interactions
Xue, Li-ping
Zhang, Yong-ge
[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2021, 722 (01) : 58 - 66
[2] Heteroleptic Zn(II)-Pentaiodobenzoate Complexes: Structures and Features of Halogen-Halogen Non-Covalent Interactions in Solid State
Bondarenko, Mikhail A.
Novikov, Alexander S.
Sokolov, Maxim N.
Adonin, Sergey A.
[J]. INORGANICS, 2022, 10 (10)
[3] Halogen bonding or close packing? Examining the structural landscape in a series of Cu(II)-acac complexes
Aakeroey, Christer B.
Sinha, Abhijeet S.
Chopade, Prashant D.
Desper, John
[J]. DALTON TRANSACTIONS, 2011, 40 (45) : 12160 - 12168
[4] The Role of Halogen Bonding in Controlling Assembly and Organization of Cu(II)-Acac Based Coordination Complexes
Gamekkanda, Janaka C.
Sinha, Abhijeet S.
Desper, John
Dakovic, Marijana
Aakeroy, Christer B.
[J]. CRYSTALS, 2017, 7 (07):
[5] Polynuclear Cu(II) complexes with hyperbranched polyester carboxylates
M. P. Kutyreva
G. Sh. Usmanova
N. A. Ulakhovich
G. A. Kutyrev
[J]. Russian Journal of General Chemistry, 2010, 80 : 787 - 789
[6] Polynuclear Cu(II) Complexes with Hyperbranched Polyester Carboxylates
Kutyreva, M. P.
Usmanova, G. Sh.
Ulakhovich, N. A.
Kutyrev, G. A.
[J]. RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2010, 80 (04) : 787 - 789
[7] Photocytotoxicity of dirhodium (II,II) complexes featuring formamidinate bridging ligands with halogen substitution
Song, Ellen
Turro, Claudia
Dunbar, Kim
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
[8] Halogen bonding in heteroleptic Cu(II) 2-iodobenzoates
Adonin, Sergey A.
Petrov, Mikhail A.
Abramov, Pavel A.
Novikov, Alexander S.
Sokolov, Maxim N.
Fedin, Vladimir P.
[J]. POLYHEDRON, 2019, 171 : 312 - 316
[9] Cu(II) complexes with a pendant octaazamacrocycle and β-bonded aromatic carboxylates
Vuckovic, G
Antonijevic, M
Poleti, D
[J]. JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2002, 67 (10) : 677 - 684
[10] A comparison of thermal characteristics of Cu(II) carboxylates and their complexes with pyridine
Petricek, S
Petric, M
[J]. THERMOCHIMICA ACTA, 1997, 302 (1-2) : 35 - 39

← 1 2 3 4 5 →