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Organic modifier induced interfacial transformation, morphology and physico-mechanical properties of PP/NR based blend nanocomposites
被引:17
|作者:
Chandran, N.
[1
]
Sarathchandran, C.
[2
]
Jose, S.
[3
]
Thankappan, S.
[1
]
Thomas, S.
[1
,4
]
机构:
[1] Mahatma Gandhi Univ, Sch Chem Sci, Kottayam 682010, Kerala, India
[2] Amrita Vishwa Vidyapeetham, Amrita Sch Engn, Chennai 601103, Tamil Nadu, India
[3] Govt Coll Kottayam, Dept Chem, Kottayam 686013, Kerala, India
[4] Mahatma Gandhi Univ, Int & Inter Univ Ctr Nanosci & Nanotechnol, Kottayam 682010, Kerala, India
关键词:
Blend;
Nanocomposites;
Interfacial properties;
Morphology;
Mechanical properties;
Reinforcements;
LOW-DENSITY POLYETHYLENE;
CARBON NANOTUBES;
NATURAL-RUBBER;
POLYMER BLENDS;
SELECTIVE LOCALIZATION;
MELT INTERCALATION;
SURFACE-ENERGY;
BEHAVIOR;
CLAY;
DISPERSION;
D O I:
10.1016/j.compositesb.2020.108045
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
The influence of incorporating organic modified nanoclay (Cloisite 10A) (C 10A) on the morphology, interfacial characteristics, and physico-mechanical properties of polypropylene (PP) melt blended with natural rubber (NR) is investigated here. Melt-mixing technique was employed to prepare nanocomposites with varying amounts of C 10A (1, 3, 5, 7 phr). Nanoclay, depending on its concentration, 'instigated dramatic transformation of phase morphology from a co-continuous type to a non-uniform sea-island type leading to well-defined matrix-droplet morphology. Besides, addition of nanoclay refined the phase morphology and effectuated synergistic improvement in physico-mechanical properties, where 3 wt% nanoclay modified system exhibited optimal properties for end use application in automotive industry thereby establishing the morphology-property correlation.
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页数:10
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