Synthesis of chromanols by tandem radical addition/cyclization mediated by tris(tri methylsilyl)silane

被引：1
|
作者：
Jaramillo-Gomez, Luz Marina [1 ]
Martin, Jaime [2 ]
Rios, Luz Amalia [3 ]
机构：
[1] Univ Valle, Dept Chem, Cali, Colombia
[2] Univ Cauca, Dept Chem, Popayan, Colombia
[3] Univ Caldas, Manizales, Colombia
来源：
JOURNAL OF THE CHILEAN CHEMICAL SOCIETY | 2007年 / 52卷 / 04期
关键词：
O-sisyl ketyl radicals; radical addition / cyclization; allyloxybenzaldehydes; chromanols; sisyl ether; tris(trimethylsilyl)silane;
D O I：
10.4067/S0717-97072007000400001
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Sisyl radicals generated from tris(trimethylsilyl)silane were reacted with allyloxy benzaldehydes and the sequential radical process of was studied. After desisylation, the corresponding chromanols were successfully obtained.
引用
收藏
页码：1277 / 1280
页数：4
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