Cobalt-Catalyzed Intermolecular C(sp2)O Cross-Coupling

被引：23

作者：

Kundu, Debasish ^{[1
]}

Tripathy, Manisha ^{[2
]}

Maity, Pintu ^{[1
]}

Ranu, Brindaban C. ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Organ Chem, Kolkata 700032, India

[2] IIT Guwahati, Dept Chem, Gauhati 781039, India

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2015年 / 21卷 / 24期

关键词：

CO coupling; cobalt; copper; ethers; homogeneous catalysis; S BOND FORMATION; SECONDARY ALKYL-HALIDES; PHOSPHINE OXIDE LIGAND; METAL-FREE ARYLATION; HECK-TYPE REACTION; ONE-POT SYNTHESIS; ARYL HALIDES; GRIGNARD-REAGENTS; VINYL HALIDES; N-ARYLATION;

D O I：

10.1002/chem.201500058

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cobalt(II)-catalyzed C(sp(2))O cross-coupling between aryl/heteroaryl alcohols and vinyl/aryl halides in the presence of Cu-I has been achieved under ligand-free conditions. In this reaction, copper plays a significant role in transmetalation rather than being directly involved in the CO coupling. This unique Co/Cu-dual catalyst system provides an easy access to a library of aryl-vinyl, heteroaryl-styryl, aryl-aryl, and heteroaryl-heteroaryl ethers in the absence of any ligand or additive.

引用

页码：8727 / 8732

页数：6

共 50 条

[1] Cobalt-Catalyzed C(sp2)-C(sp3) Cross-Coupling Reactions of Diarylmanganese Reagents with Secondary Alkyl Iodides
Hofmayer, Maximilian S.
Hammann, Jeffrey M.
Haas, Diana
Knochel, Paul
[J]. ORGANIC LETTERS, 2016, 18 (24) : 6456 - 6459
[2] Cobalt-Catalyzed C(sp2)-C(sp3) Suzuki-Miyaura Cross Coupling
Ludwig, Jacob R.
Simmons, Eric M.
Wisniewski, Steven R.
Chirik, Paul J.
[J]. ORGANIC LETTERS, 2021, 23 (03) : 625 - 630
[3] Cobalt-catalyzed cross-coupling reactions
Gosmini, Corinne
Begouin, Jeanne-Marie
Moncomble, Aurelien
[J]. CHEMICAL COMMUNICATIONS, 2008, (28) : 3221 - 3233
[4] Cobalt-Catalyzed Cross-Coupling Reactions
Cahiez, Gerard
Moyeux, Alban
[J]. CHEMICAL REVIEWS, 2010, 110 (03) : 1435 - 1462
[5] Ni-catalyzed C(sp2)-carbon and C(sp2)-heteroatom cross-coupling reactions
Li, Z
Fu, Y
Liu, L
Guo, QX
[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2005, 25 (12) : 1508 - 1529
[6] Cobalt-Catalyzed Cross-Dehydrogenative C(sp2)-C(sp3) Coupling of Oxazole/Thiazole with Ether or Cycloalkane
Wang, Xiaojiao
Lei, Bowen
Ma, Lifang
Zhu, Lisi
Zhang, Xinyue
Zuo, Hao
Zhuang, Dailin
Li, Ziyuan
[J]. CHEMISTRY-AN ASIAN JOURNAL, 2017, 12 (21) : 2799 - 2803
[7] A Cobalt-Catalyzed Enantioconvergent Radical Negishi C(sp3) - C(sp2) Cross-Coupling with Chiral Multidentate N,N,P-Ligand
Li, Zhuang
Cheng, Xian-Yan
Yang, Ning-Yuan
Chen, Ji-Jun
Tang, Wen-Yue
Bian, Jun-Qian
Cheng, Yong-Feng
Li, Zhong-Liang
Gu, Qiang-Shuai
Liu, Xin-Yuan
[J]. ORGANOMETALLICS, 2021, 40 (14) : 2215 - 2219
[8] Cobalt-NHC Catalyzed C(sp2)-C(sp3) and C(sp2)-C(sp2) Kumada Cross-Coupling of Aryl Tosylates with Alkyl and Aryl Grignard Reagents
Piontek, Aleksandra
Ochedzan-Siodlak, Wioletta
Bisz, Elwira
Szostak, Michal
[J]. CHEMCATCHEM, 2021, 13 (01) : 202 - 206
[9] Cobalt-Catalyzed Green Cross-Dehydrogenative C(sp2)-H/P-H Coupling Reactions
Khrizanforov, Mikhail
Strekalova, Sofia
Khrizanforova, Vera
Dobrynin, Alexey
Kholin, Kirill
Gryaznova, Tatyana
Grinenko, Valeriya
Gubaidullin, Aidar
Kadirov, M. K.
Budnikova, Yulia
[J]. TOPICS IN CATALYSIS, 2018, 61 (18-19) : 1949 - 1956
[10] Cobalt-Catalyzed Green Cross-Dehydrogenative C(sp2)-H/P-H Coupling Reactions
Mikhail Khrizanforov
Sofia Strekalova
Vera Khrizanforova
Alexey Dobrynin
Kirill Kholin
Tatyana Gryaznova
Valeriya Grinenko
Aidar Gubaidullin
M. K. Kadirov
Yulia Budnikova
[J]. Topics in Catalysis, 2018, 61 : 1949 - 1956

← 1 2 3 4 5 →