Vitamin B1-catalyzed aerobic oxidative esterification of aromatic aldehydes with alcohols

被引:9
|
作者
Luo, Xin-Long [1 ]
Ge, Danhua [1 ]
Yu, Zi-Lun [1 ]
Chu, Xue-Qiang [1 ]
Xu, Pei [2 ]
机构
[1] Nanjing Tech Univ, Sch Chem & Mol Engn, Nanjing 211816, Peoples R China
[2] Xuzhou Med Univ, Sch Pharm, Jiangsu Key Lab New Drug Res & Clin Pharm, Xuzhou 221004, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
ONE-POT SYNTHESIS; THIAMINE HYDROCHLORIDE VB1; EFFICIENT PROMOTER; CARBOXYLIC-ACIDS; DERIVATIVES; CONDENSATION; ACYLATION; CATALYST; WATER;
D O I
10.1039/d1ra05134b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A straightforward aerobic oxidative esterification of aryl aldehydes with alcohols has been developed for the synthesis of substituted esters by employing vitamin B1 as a cost-effective, metal-free, and eco-friendly NHC catalyst. Air is used as a green terminal oxidant. The reaction is a useful addition to the existing NHC-catalytic oxidative esterification.
引用
收藏
页码:30937 / 30942
页数:6
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