Promoting Effect of Triglyme on Lean NOx Reduction Over Ag/Al2O3

被引:0
|
作者
Erkfeldt, Sara [1 ,2 ]
Palmqvist, Anders [2 ]
机构
[1] Volvo Technology Corp, Dept 6130, S-41288 Gothenburg, Sweden
[2] Chalmers, Dept Chem & Biol Engn, Competence Ctr Catalysis, S-41296 Gothenburg, Sweden
基金
瑞典研究理事会;
关键词
Hydrocarbon-SCR; NOx Reduction; Alumina; Triglyme; Ether; Propene; Ag/Al2O3; Cu-ZSM-5; SELECTIVE CATALYTIC-REDUCTION; HYDROCARBONS; HYDROGEN; C2H5OH; OXIDE; MECHANISM; PROPENE; C3H6;
D O I
10.1007/s10562-011-0760-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The highly oxygenated hydrocarbon triethylene glycol dimethyl ether or triglyme (CH3O-(C2H4O-)(3)CH3) was found to efficiently reduce NOx under lean conditions over Ag/Al2O3, but gave a low NOx conversion over Cu-ZSM-5. Furthermore, triglyme showed an extraordinary promoting effect when added together with propene as reducing agent for NOx over Ag/Al2O3 at low temperature. This is most likely due to that triglyme promotes the activation of propene.
引用
收藏
页码:183 / 189
页数:7
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