Lanthanide porphyrazine sandwich complexes: synthetic, structural and spectroscopic investigations

被引：0
|
作者：
Montalban, AG
Michel, SLJ
Baum, SM
Vesper, BJ
White, AJP
Williams, DJ
Barrett, AGM
Hoffman, BM
机构：
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England
[2] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 22期
关键词：
D O I：
10.1039/b103346h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of four novel lanthanide tetraazaporphyrin (porphyrazine) sandwich complexes is reported: [Ce( OPTAP)(2)] (2), [Lu(OPTAP)(2)] (3), [Eu(OPTAP)(2)] (4) and [Eu-2 (OPTAP)(3)] (5) (OPTAP = 2,3,7,8,12,13,17,18-octapropyltetraazaporphyrinato). The structure of 2 has been unequivocally established by an X-ray crystallographic study. The radical nature of 3 and 4 has been confirmed by UV-vis, IR, and EPR spectroscopy. Cyclic voltammetry results show that 2-5 are more easily oxidized than 1 (H(2)OPTAP) by 0.41, 0.56, 0.48 and 0.40 V respectively.
引用
收藏
页码：3269 / 3273
页数：5
相关论文
共 50 条
  • [41] Synthesis, spectroscopic and single-crystal structural investigations of several lanthanide hexacyanoruthenate(II) tetrahydrates
    Department of Chemistry, Baylor University, Waco, TX 76798, United States
    Inorg. Chim. Acta, 2 (273-276):
  • [42] TERT-BUTYLPEROXO COMPLEXES OF PLATINUM(II) - SYNTHETIC, SPECTROSCOPIC, AND STRUCTURAL INVESTIGATIONS - OXYGENATION OF 1-OCTENE BY TRANS SPECIES
    STRUKUL, G
    MICHELIN, RA
    ORBELL, JD
    RANDACCIO, L
    INORGANIC CHEMISTRY, 1983, 22 (25) : 3706 - 3713
  • [43] Synthetic and structural investigations of alkali metal diamine bis(phenolate) complexes
    Clegg, William
    Davidson, Matthew G.
    Graham, David V.
    Griffen, Gemma
    Jones, Matthew D.
    Kennedy, Alan R.
    O'Hara, Charles T.
    Russo, Luca
    Thomson, Calum M.
    DALTON TRANSACTIONS, 2008, (10) : 1295 - 1301
  • [44] Synthetic and structural investigations of alkali metal diamine bis(phenolate) complexes
    School of Natural Sciences , Newcastle University, Newcastle-upon-Tyne NE1 7RU, United Kingdom
    不详
    不详
    Dalton Trans., 2008, 10 (1295-1301):
  • [45] Cyanomethylene-bis(phosphonate)-Based Lanthanide Complexes: Structural, Photophysical, and Magnetic Investigations
    Maxim, Catalin
    Branzea, Diana G.
    Tiseanu, Carmen
    Rouzieres, Mathieu
    Clerac, Rodolphe
    Andruh, Marius
    Avarvari, Narcis
    INORGANIC CHEMISTRY, 2014, 53 (05) : 2708 - 2717
  • [46] Laser spectroscopic and computational insights into unexpected structural behaviours of sandwich complexes upon ionization
    Ketkov, Sergey Yu.
    Tzeng, Sheng-Yuan
    Rychagova, Elena A.
    Markin, Gennady V.
    Makarov, Sergei G.
    Tzeng, Wen-Bih
    DALTON TRANSACTIONS, 2021, 50 (31) : 10729 - 10736
  • [47] Photophysics of lanthanide triple decker porphyrin sandwich complexes
    Wittmer, LL
    Holten, D
    JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (02): : 860 - 868
  • [48] Lanthanide complexes of new ditopic, tripodal macrocycles: synthetic, structural, stability and luminescence studies
    Murphy, BP
    Quinti, L
    Kelly, DG
    Martin, WJ
    Perotti, A
    Hursthouse, MB
    Gelbrich, T
    INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (08) : 577 - 580
  • [49] Synthetic and spectroscopic investigations of some transition metal complexes of hydroxy-oxime ligand
    El-Tabl, AS
    JOURNAL OF CHEMICAL RESEARCH-S, 2004, (01): : 19 - 22
  • [50] Synthetic and spectroscopic investigations of N(4)-substituted isatin thiosemicarbazones and their copper(II) complexes
    Bain, GA
    West, DX
    Krejci, J
    ValdesMartinez, J
    HernandezOrtega, S
    Toscano, RA
    POLYHEDRON, 1997, 16 (05) : 855 - 862
12345