Decarboxylative C(sp3)-S Coupling via Cu-Photoredox Catalysis

被引：2
|
作者：
Bakhoda, Abolghasem [1 ]
Warren, Timothy H. [2 ]
机构：
[1] Natl Inst Alcohol Abuse & Alcoholism, NIH, Bethesda, MD 20892 USA
[2] Georgetown Univ, Dept Chem, Washington, DC 20057 USA
来源：
CHEM | 2020年 / 6卷 / 05期
基金：
美国国家科学基金会;
关键词：
SULFONYLATION;
D O I：
10.1016/j.chempr.2020.04.018
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this issue of Chem, Liu, Li, and co-workers report the synergistic use of copper and photoredox catalysis to reveal a general platform to form C(sp(3))-S bonds via redox-active esters of abundantly available aliphatic carboxylic acids with organosulfinates under mild conditions.
引用
收藏
页码：1048 / 1050
页数：4
相关论文
共 50 条
  • [41] Oxidation induced C(sp3)-O cleavage via visible-light photoredox catalysis
    Wang, Shengchun
    Liu, Jiamei
    Niu, Linbin
    Yi, Hong
    Chiang, Chien-Wei
    Lei, Aiwen
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2018, 355 : 120 - 124
  • [42] Cu-Photoredox-catalyzed C(sp)-C(sp3) coupling of redox-active esters with terminal alkynes
    Zhang, Yajing
    Zhang, Dayong
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2020, 18 (23) : 4479 - 4483
  • [43] Iron-catalyzed alkenylation of cyclic ethers via decarboxylative sp3(C)-sp2(C) coupling
    Zhao, Jincan
    Zhou, Wei
    Han, Jianlin
    Li, Guigen
    Pan, Yi
    TETRAHEDRON LETTERS, 2013, 54 (48) : 6507 - 6510
  • [44] Silver-catalyzed decarboxylative C(sp2)-C(sp3) coupling reactions via a radical mechanism
    Fang, Zhongxue
    Wei, Chenlong
    Lin, Jing
    Liu, Zhenhua
    Wang, Wei
    Xu, Chenshu
    Wang, Xuemin
    Wang, Yu
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2017, 15 (47) : 9974 - 9978
  • [45] Copper-catalyzed decarboxylative C(sp2)-C(sp3) coupling reactions via radical mechanism
    Yang, Hailong
    Sun, Peng
    Zhu, Yan
    Yan, Hong
    Lu, Linhua
    Qu, Xiaoming
    Li, Tingyi
    Mao, Jincheng
    CHEMICAL COMMUNICATIONS, 2012, 48 (63) : 7847 - 7849
  • [46] Modular access to saturated bioisosteres of anilines via photoelectrochemical decarboxylative C(sp3)-N coupling
    Yuan, Kang-Ning
    Zhuang, Hongjun
    Wei, Jie
    Shen, Yu
    Yao, Hong-Qing
    Li, Ming-Hong
    Xu, Lin-Lin
    Shang, Ming
    NATURE COMMUNICATIONS, 2025, 16 (01)
  • [47] Tandem Photoredox and Copper-Catalyzed Decarboxylative C(sp3)-N Coupling of Anilines and Imines Using an Organic Photocatalyst
    Barzano, Guido
    Mao, Runze
    Garreau, Marion
    Waser, Jerome
    Hu, Xile
    ORGANIC LETTERS, 2020, 22 (14) : 5412 - 5416
  • [48] C(sp3)-C(sp3) Coupling of Cycloalkanes and Alkyl Halides via Dual Photocatalytic Hydrogen Atom Transfer and Nickel Catalysis
    Pilli, Ramadevi
    Selvam, Keerthika
    Balamurugan, Bala S. S.
    Jose, Vidya
    Rasappan, Ramesh
    ORGANIC LETTERS, 2024, 26 (15) : 2993 - 2998
  • [49] Photoelectrocatalyzed Alkylation of Phosphonites by Direct Decarboxylative C(sp3)-P Coupling
    Yuan, Kang-Ning
    Xie, Tian
    Wang, Jia-Bao
    Wang, Dali
    Shang, Ming
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2025,
  • [50] Direct C(sp3)-H difluoromethylation via radical-radical cross-coupling by visible-light photoredox catalysis
    Xiong, Wei
    Qin, Wen-Bing
    Zhao, Ya-Shi
    Fu, Kai-Zhong
    Liu, Guo-Kai
    Organic Chemistry Frontiers, 2022, 9 (08) : 2141 - 2148
12345