Uniform Distribution of Pd on GO-C Catalysts for Enhancing the Performance of Air Cathode Microbial Fuel Cell

被引:8
|
作者
Wang, Jingzhen [1 ,2 ]
Mu, Kaijie [2 ]
Zhao, Xuedong [2 ]
Luo, Dianliang [2 ]
Yu, Xiaodi [2 ]
Li, Wenpeng [3 ,4 ]
Chu, Jie [5 ]
Yang, Jing [6 ]
Yang, Qinzheng [1 ,2 ]
机构
[1] Qilu Univ Technol, Shandong Acad Sci, State Key Lab Biobased Mat & Green Papermaking, Jinan 250353, Peoples R China
[2] Qilu Univ Technol, Shandong Acad Sci, Dept Bioengn, Jinan 250353, Peoples R China
[3] Qilu Univ Technol, Shandong Acad Sci, Engn & Technol Ctr Electrochem, Sch Chem & Chem Engn, Jinan 250353, Peoples R China
[4] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Shandong Key Lab Biochem Anal, Qingdao 266042, Peoples R China
[5] Qilu Univ Technol, Shandong Acad Sci, Biol Inst, Jinan 250103, Peoples R China
[6] Qilu Univ Technol, Shandong Acad Sci, Sch Elect & Informat Engn, Dept Phys, Jinan 250353, Peoples R China
基金
中国国家自然科学基金;
关键词
oxygen reduction reaction; microbial fuel cell; air cathode; OXYGEN REDUCTION REACTION; SUPPORTED PD; CARBON; ELECTROCATALYSTS; NANOPARTICLES; PALLADIUM; BLACK; ELECTRODE; FE;
D O I
10.3390/catal11080888
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Metal, as a high-performance electrode catalyst, is a research hotspot in the construction of a high-performance microbial fuel cell (MFC). However, metal catalyst nanoparticles and their dispersed carriers are prone to aggregation, producing catalytic electrodes with inferior qualities. In this study, Pd is uniformly dispersed on the graphene framework supported by carbon black to form nanocomposite catalysts (Pd/GO-C catalysts). The effect of the palladium loading amount in the catalyst on the catalytic performance of the air cathode was further studied. The optimized metal loading afforded a reduced resistance and improved accessibility of Pd particles for the ORR. The maximum current output of the 0.250 Pd (mg/cm(2)) MFC was 1645 mA/m(2), which is 4.2-fold higher than that of the carbon paper cathode. Overall, our findings provide a novel protocol for the preparation of high-efficient ORR catalyst for MFCs.
引用
收藏
页数:11
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