Recent Advances in the C(sp2)-S Bond Formation Reactions by Transition Metal-Free C(sp2)-H Functionalization

被引：42
|
作者：
Liu, Yunyun [1 ]
Xiong, Jin [1 ]
Wei, Li [1 ]
机构：
[1] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 37卷 / 07期
基金：
中国国家自然科学基金;
关键词：
transition metal-free; C(sp(2))-H bond; (Hetero)aryl; vinyl; C(sp(2))-S bond formation; CATALYZED REGIOSELECTIVE SULFENYLATION; PROMOTED DIRECT SULFENYLATION; CROSS-COUPLING REACTIONS; C-H SULFENYLATION; SULFONYL HYDRAZIDES; QUINONE MONO-O; S-ACETALS; ARYLSULFONYL CHLORIDES; ARYL SULFIDES; BUNTE SALTS; FREE SYSTEM;
D O I：
10.6023/cjoc201702009
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Aryl/vinyl thioethers containing C(sp(2))-S bonds are prevalent in biologically relevant molecules and compounds with other potential applications. Around the past decade, rapid progress has taken place in the research area of C(sp(2))-S construction, and a large number of efficient new catalytic systems as well as structurally versatile substrates have been identified for such reactions, which significantly enriched the content of the synthetic methodologies on C(sp(2))-S bond formation. This review introduces mainly the research advances on transition metal-free C(sp(2))-S bond forming reaction by means of C(sp(2))-H bond functionalization over the period of 2001 similar to 2016.
引用
收藏
页码：1667 / 1680
页数：14
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