Polymeric capsules and honeycomb aggregates formed by p-sulfonatocalix[6]arene with phenanthrolinium compounds

被引：22
|
作者：
Liu, Yu [1 ]
Li, Qiang [1 ]
Guo, Dong-Sheng [1 ]
Chen, Kun [1 ]
机构：
[1] Nankai Univ, State Key Lab Elementoorgan Chem, Dept Chem, Tianjin 300071, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2007年 / 7卷 / 09期
关键词：
D O I：
10.1021/cg0704854
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two crystalline complexes were prepared by the inclusion complexation of p-sulfonatocalix [6]arene (C6AS) with 1,10-phenanthrolinium (Phen(+)) (1) and 6,7-dihydro-5H-[1,4]diazepino[1,2,3,4-lmn] [1,10]phenanthroline-4,8-diium (PPQ(2+)) (2). p-Sulfonatocalix [6]arene, in complex 1, maintains the conventional centrosymmetric "up-down" double partial cone conformation, whereas it assumes a novel unsymmetric up-down double partial cone conformation induced by PPQ(2+) guest in complex 2. Furthermore, p-sulfonatocalix [6]arene aggregates to the overall structure of multipillars in the presence of Phen+ guest and presents the honeycomb-type packing structure upon complexation with PPQ(2+).
引用
收藏
页码：1672 / 1675
页数：4
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