Benzyltriphenylphosphonium peroxodisulfate (PhCH2PPh3)2S2O8:: a mild and inexpensive reagent for efficient oxidation of organic compounds under nonaqueous and aprotic conditions

被引：38
|
作者：
Mohammadpoor-Baltork, I [1 ]
Hajipour, AR
Mohammadi, H
机构：
[1] Esfahan Univ, Dept Chem, Esfahan 81744, Iran
[2] Esfahan Univ Technol, Coll Chem, Esfahan 84156, Iran
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1998年 / 71卷 / 07期
关键词：
D O I：
10.1246/bcsj.71.1649
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Benzyltriphenylphosphonium peroxodisulfate is an easily prepared and stable reagent. It could be used as an oxidant under aprotic and nonaqueous conditions in organic solvents. This reagent oxidizes different classes of alcohols to carbonyl compounds, thiols to disulfides, sulfides to sulfoxides, oximes to carbonyl compounds and aromatic amines to azo compounds efficiently, alpha-Hydroxy carboxylic acids and phenylacetic acids undergo oxidative decarboxylation to produce carbonyl compounds.
引用
收藏
页码：1649 / 1653
页数：5
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