Advances in Visible-Light-Mediated Carbonylative Reactions via Carbon Monoxide (CO) Incorporation

被引：21

作者：

Botla, Vinayak ^{[1
]}

Voronov, Aleksandr ^{[1
]}

Motti, Elena ^{[1
]}

Carfagna, Carla ^{[2
]}

Mancuso, Raffaella ^{[3
]}

Gabriele, Bartolo ^{[3
]}

Della Ca, Nicola ^{[1
]}

机构：

[1] Univ Parma, Dept Chem Life Sci & Environm Sustainabil SCVSA, Parco Area Sci 17-A, I-43124 Parma, Italy

[2] Univ Bologna, Dept Ind Chem T Montanari, I-40136 Bologna, Italy

[3] Univ Calabria, Lab Ind & Synthet Organ Chem LISOC, Dept Chem & Chem Technol, Via P Bucci 12-C, I-87036 Arcavacata Di Rende Cose, Italy

来源：

CATALYSTS | 2021年 / 11卷 / 08期

关键词：

carbon monoxide; carbonylation; photochemical reactions; visible light; carbonyl-containing compounds; ATOM-TRANSFER CARBONYLATION; ALKYL IODIDES; METAL-COMPLEXES; CATALYZED AMINOCARBONYLATION; RADICAL AMINOCARBONYLATION; COUPLING REACTION; ARYL KETONES; PALLADIUM; HALIDES; DERIVATIVES;

D O I：

10.3390/catal11080918

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The abundant and inexpensive carbon monoxide (CO) is widely exploited as a C1 source for the synthesis of both fine and bulk chemicals. In this context, photochemical carbonylation reactions have emerged as a powerful tool for the sustainable synthesis of carbonyl-containing compounds (esters, amides, ketones, etc.). This review aims at giving a general overview on visible light-promoted carbonylation reactions in the presence of metal (Palladium, Iridium, Cobalt, Ruthenium, Copper) and organocatalysts as well, highlighting the main features of the presented protocols and providing useful insights on the reaction mechanisms.

引用

页数：35

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