Growth of Methane Clathrate Hydrates in Porous Media

被引：67

作者：

Jin, Yusuke ^{[1
]}

Konno, Yoshihiro ^{[1
]}

Nagao, Jiro ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Methane Hydrate Res Ctr, Prod Technol Team, Toyohira Ku, Sapporo, Hokkaido 0628517, Japan

来源：

ENERGY & FUELS | 2012年 / 26卷 / 04期

关键词：

GAS-HYDRATE; CRYSTAL-GROWTH; CARBON-DIOXIDE; NANKAI TROUGH; FILM GROWTH; DISSOCIATION; DIFFRACTION; CORES; CO2;

D O I：

10.1021/ef3001357

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The growth processes of methane hydrates in porous media were investigated using attenuated total reflection infrared (ATR-IR) spectroscopic and optical microscopic techniques. The ATR-IR spectra revealed that hydrates in porous media grew in two steps. Discrete hydrate growth in two steps was observed, despite several degrees of subcooling. In the first step, film-like hydrates were formed at the gas water interface. Visual observations showed that the hydrate films collapsed and then fresh liquid-phase H2O molecules, from the cracks in the film, entered the hydrate phase. In porous media, the cracks in the hydrate film were found to change the nature of the hydrate from a film to a cement-like hydrate. Two-step growth reflects the change in the nature of hydrates formed in porous media.

引用

页码：2242 / 2247

页数：6

共 50 条

[41] In situ observation of gas hydrates growth hosted in porous media
Xue, K., 1600, Elsevier B.V., Netherlands (612):
[42] CLATHRATE HYDRATES
MOOTZ, D
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1988, 182 (1-4): : 187 - 188
[43] Stability of methane clathrate hydrates under pressure: Influence on outgassing processes of methane on Titan
Choukroun, Mathieu
Grasset, Olivier
Tobie, Gabriel
Sotin, Christophe
ICARUS, 2010, 205 (02) : 581 - 593
[44] CLATHRATE HYDRATES
ENGLEZOS, P
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1993, 32 (07) : 1251 - 1274
[45] Clathrate hydrates
Buffett, BA
ANNUAL REVIEW OF EARTH AND PLANETARY SCIENCES, 2000, 28 : 477 - 507
[46] Storage of Methane in Clathrate Hydrates: Monte Carlo Simulations of sI Hydrates and Comparison with Experimental Measurements
Papadimitriou, Nikolaos I.
Tsimpanogiannis, Ioannis N.
Economou, Loannis G.
Stubos, Athanassios K.
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2016, 61 (08): : 2886 - 2896
[47] Effect of Ammonium Fluoride Doping on Nitrogen, Oxygen, and Methane Clathrate Hydrates
Lee, Byeonggwan
Shin, Kyuchul
Alavi, Saman
Ripmeester, John A.
ENERGY & FUELS, 2022, 36 (18) : 11123 - 11131
[48] Prediction of phase stability conditions of gas hydrates of methane and carbon dioxide in porous media
Barmavath, Tejaswi
Mekala, Prathyusha
Sangwai, Jitendra S.
JOURNAL OF NATURAL GAS SCIENCE AND ENGINEERING, 2014, 18 : 254 - 262
[49] Vibrational spectra of methane clathrate hydrates from molecular dynamics simulation
Greathouse, JA
Cygan, RT
Simmons, BA
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (13): : 6428 - 6431
[50] Nuclear Magnetic Resonance Parameters for Methane Molecule Trapped in Clathrate Hydrates
Siuda, Pawel
Sadlej, Joanna
JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 115 (05): : 612 - 619

← 1 2 3 4 5 →