Radical aryl migration reactions and synthetic applications

被引：305

作者：

Chen, Zhi-Min ^{[1
]}

Zhang, Xiao-Ming ^{[2
,3
]}

Tu, Yong-Qiang ^{[1
,2
,3
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China

[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

[3] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2015年 / 44卷 / 15期

关键词：

O-NEOPHYL REARRANGEMENT; ALPHA; ALPHA-DIARYL ALLYLIC ALCOHOLS; ELECTRON-SPIN-RESONANCE; INTRAMOLECULAR IPSO SUBSTITUTION; ABSOLUTE RATE CONSTANTS; C BOND FORMATION; THERMAL-DECOMPOSITION; ELECTROCHEMICAL REACTIONS; 1,4-ARYL MIGRATION; CATALYZED TRIFLUOROMETHYLATION;

D O I：

10.1039/c4cs00467a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Radical aryl migration reactions are of particular interest to the chemical community due to their potential application in radical chemistry and organic synthesis. The neophyl rearrangements used as radical clocks for examining the radical-molecular reactions have been known for decades. The combinations of these migrations with other radical reactions have provided a wide range of novel synthetic methodologies that are complementary to nucleophilic rearrangements. This review will give an overview of various types of radical aryl migrations, with an emphasis on their mechanistic studies from a historical point of view, as well as their application in tandem radical reactions.

引用

页码：5220 / 5245

页数：26

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