Bimetallic Al/Fe Metal-Organic Framework for highly efficient photo-Fenton degradation of rhodamine B under visible light irradiation

被引:43
|
作者
Nguyen, Hong-Tham T. [1 ,2 ,3 ]
Dinh, Van-Phuc [4 ,5 ]
Phan, Quynh-Anh N. [1 ,2 ]
Tran, Vy Anh [6 ]
Doan, Van-Dat [7 ]
Lee, Taeyoon [8 ]
Nguyen, Trinh Duy [3 ,8 ]
机构
[1] Ho Chi Minh City Univ Technol HCMUT, Fac Chem Engn, 268 Ly Thuong Kiet,Dist 10, Ho Chi Minh City, Vietnam
[2] Vietnam Natl Univ Ho Chi Minh City, Ho Chi Minh City, Vietnam
[3] Nguyen Tat Thanh Univ, Ctr Excellence Green Energy & Environm Nanomat CE, Ho Chi Minh City, Vietnam
[4] Duy Tan Univ, Inst Fundamental & Appl Sci, Future Mat & Devices Lab, Ho Chi Minh City 700000, Vietnam
[5] Duy Tan Univ, Fac Nat Sci, Da Nang 550000, Vietnam
[6] Gachon Univ, Dept Chem & Biochem Engn, 1342 Seongnamdaero, Seongnam Si 13120, South Korea
[7] Ind Univ Ho Chi Minh City, Fac Chem Engn, Ho Chi Minh City, Vietnam
[8] Pukyong Natl Univ, Coll Environm & Marine, Dept Environm Engn, 45 Yongso Ro, Busan 48513, South Korea
关键词
Bimetallic Al/Fe Metal-Organic Framework; Photo-Fenton degradation of rhodamine B; Visible light irradiation; PHOTOCATALYTIC DEGRADATION; MIL-88B;
D O I
10.1016/j.matlet.2020.128482
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
MIL-88B(Fe) (MIL: Materials Institute Lavoisier) and bimetallic Al/Fe Metal-Organic Framework (Al/FeMOF) were synthesized by the microwave-assistant method. The as-synthesized samples were used as an effective catalyst for photo-Fenton degradation of rhodamine B (RhB) under visible light irradiation. The Al/Fe-MOF catalyst caused to degrade more than 96% of RhB in up to 120 min with the rate of reaction reached 2.8 x 10(-2) min(-1), while the rate achieved using MIL-88B(Fe) reached 1.2 x 10(-2) min(-1). Besides, the reaction mechanism of RhB photo-Fenton degradation process over Al/Fe-MOF also investigated. These results indicate that Al/Fe-MOF has been considered as a potential catalyst for wastewater treatment. (C) 2020 Elsevier B.V. All rights reserved.
引用
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页数:4
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