Palladium-catalyzed decarboxylative O-allylation of phenols with γ-methylidene-δ-valerolactones

被引：4
|
作者：
Song, Ran [1 ]
Lian, Zhendong [1 ]
Feng, Wei [1 ]
Guan, Tianyi [1 ]
Si, Wen [1 ]
Yang, Daoshan [1 ]
Lv, Jian [1 ]
机构：
[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Key Lab Opt Elect Sensing & Analyt Chem Life Sci, MOE, Qingdao 266042, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2022年 / 9卷 / 16期
关键词：
INTERMOLECULAR ALLYLIC ETHERIFICATION; ENANTIOSELECTIVE SYNTHESIS; DEHYDRATIVE ALLYLATION; BOND FORMATION; ARYL; ALCOHOLS; ALKYLATION; CYCLOADDITION; OXYGEN; ATTACK;
D O I：
10.1039/d2qo00444e
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel palladium-catalyzed decarboxylative O-allylation of phenols was developed, in which a gamma-methylidene-delta-valerolactone (GMDV) was found to be an efficient and selective allylation reagent, affording the target allyl phenyl ethers in up to 92% yields under mild conditions.
引用
收藏
页码：4365 / 4371
页数：7
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