Palladium-catalyzed decarboxylative O-allylation of phenols with γ-methylidene-δ-valerolactones

被引：4

作者：

Song, Ran ^{[1
]}

Lian, Zhendong ^{[1
]}

Feng, Wei ^{[1
]}

Guan, Tianyi ^{[1
]}

Si, Wen ^{[1
]}

Yang, Daoshan ^{[1
]}

Lv, Jian ^{[1
]}

机构：

[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Key Lab Opt Elect Sensing & Analyt Chem Life Sci, MOE, Qingdao 266042, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2022年 / 9卷 / 16期

关键词：

INTERMOLECULAR ALLYLIC ETHERIFICATION; ENANTIOSELECTIVE SYNTHESIS; DEHYDRATIVE ALLYLATION; BOND FORMATION; ARYL; ALCOHOLS; ALKYLATION; CYCLOADDITION; OXYGEN; ATTACK;

D O I：

10.1039/d2qo00444e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel palladium-catalyzed decarboxylative O-allylation of phenols was developed, in which a gamma-methylidene-delta-valerolactone (GMDV) was found to be an efficient and selective allylation reagent, affording the target allyl phenyl ethers in up to 92% yields under mild conditions.

引用

页码：4365 / 4371

页数：7

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