Synthesis, characterization, and oxidation catalysis of a novel Dawson polyoxometalatesupported platinum(II) complex, [{Pt(cod)}(P2W15V3O62)]7- (cod=1,5-cyclooctadiene)

被引：11

作者：

Nomiya, K ^{[1
]}

Torii, H ^{[1
]}

Kato, CN ^{[1
]}

Sado, Y ^{[1
]}

机构：

[1] Kanagawa Univ, Fac Sci, Dept Mat Sci, Hiratsuka, Kanagawa 2591293, Japan

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 07期

关键词：

D O I：

10.1246/cl.2003.664

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel Dawson polyoxotungstate-based organometallic platinum(II) complex, [{Pt(cod)}(P2W15V3O62)](7-) (cod = 1,5-cyclooctadiene), which showed effective catalytic activity for oxidation of cyclohexanol with 30% aqueous hydrogen peroxide, was synthesized and spectroscopically characterized.

引用

页码：664 / 665

页数：2

共 26 条

[21] Synthesis and characterization of a monoruthenium(III)-substituted Dawson polyoxotungstate derived by Br2 oxidation of the 1:2 complex of ruthenium(II) and [α2-P2W17O61]10-.: The reactivity of cis-[RuCl2(DMSO)4] as a ruthenium source
Nomiya, K
Torii, H
Nomura, K
Sato, Y
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (09): : 1506 - 1512
[22] The all-sodium salt of a polyoxoanion-supported organometallic complex: synthesis and characterization of Na7[(eta5-C5Me5)Rh QQ P2W15Nb3O62] QQ 7DMSO QQ 5H2O
Nomiya, K.
Nozaki, C.
Kaneko, M.
Finke, R. G.
Journal of Organometallic Chemistry,
[23] Preparation and characterization of a novel Wells-Dawson heteropolyacid-based magnetic inorganic-organic nanohybrid catalyst H6P2W18O62/pyridino-Fe3O4 for the efficient synthesis of 1-amidoalkyl-2-naphthols under solvent-free conditions
Tayebee, Reza
Amini, Mostafa M.
Rostamian, Hooriyeh
Aliakbari, Azam
DALTON TRANSACTIONS, 2014, 43 (04) : 1550 - 1563
[24] The all-sodium salt of a polyoxoanion-supported organometallic complex: Synthesis and characterization of Na-7[(eta(5)-C(5)Me(5))Rh center dot P2W15Nb3O62]center dot 7DMSO center dot 5H(2)O
Nomiya, K
Nozaki, C
Kaneko, M
Finke, RG
Pohl, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 505 (01) : 23 - 28
[25] TRISUBSTITUTED HETEROPOLYTUNGSTATES AS SOLUBLE METAL-OXIDE ANALOGS .3. SYNTHESIS, CHARACTERIZATION, P-31, SI-29, V-51, AND 1-D AND 2-D W-183 NMR, DEPROTONATION, AND H+ MOBILITY STUDIES OF ORGANIC-SOLVENT SOLUBLE FORMS OF HXSIW9V3O40X-7 AND HXP2W15V3O62X-9
FINKE, RG
RAPKO, B
SAXTON, RJ
DOMAILLE, PJ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (11) : 2947 - 2960
[26] Co-oxidative epoxidation of cyclohexene with molecular oxygen, isobutyraldehyde reductant, and the polyoxoanion-supported catalyst precursor [(n-C4H9)(4)N](5)Na-3[(1,5-COD)Ir center dot P2W15Nb3O62]. The importance of key control experiments including omitting the catalyst and adding radical-chain initiators.
Mizuno, N
Weiner, H
Finke, RG
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 114 (1-3) : 15 - 28

← 1 2 3 →