Synthesis, characterization, and oxidation catalysis of a novel Dawson polyoxometalatesupported platinum(II) complex, [{Pt(cod)}(P2W15V3O62)]7- (cod=1,5-cyclooctadiene)

被引：11

作者：

Nomiya, K ^{[1
]}

Torii, H ^{[1
]}

Kato, CN ^{[1
]}

Sado, Y ^{[1
]}

机构：

[1] Kanagawa Univ, Fac Sci, Dept Mat Sci, Hiratsuka, Kanagawa 2591293, Japan

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 07期

关键词：

D O I：

10.1246/cl.2003.664

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel Dawson polyoxotungstate-based organometallic platinum(II) complex, [{Pt(cod)}(P2W15V3O62)](7-) (cod = 1,5-cyclooctadiene), which showed effective catalytic activity for oxidation of cyclohexanol with 30% aqueous hydrogen peroxide, was synthesized and spectroscopically characterized.

引用

页码：664 / 665

页数：2

共 26 条

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Nomiya, Kenji
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INORGANICA CHIMICA ACTA, 2007, 360 (07) : 2313 - 2320
[2] Pd-Containing Organopolyoxometalates Derived from Dawson Polyoxometalate [P2W15V3O62]9-: Lewis Acidity and Dual Site Catalysis
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ORGANIC LETTERS, 2014, 16 (15) : 3860 - 3863
[3] Reaction of [(COD)RhCl](2) (COD=1,5-cyclooctadiene) with 6,6-dimethyl-fulvene and i-C3H7MgBr: Synthesis, isolation and structural characterization of new pi-complexes of rhodium
Muller, J
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QUIMICA NOVA, 1996, 19 (06): : 613 - 619
[4] The room temperature substitution of n- and iso-perfluoropropyl iodides and n-perfluorobutyl iodide to dimethylplatinum (II) 1,5-cyclooctadiene:: The crystal structure of [Pt(C3F7)2(COD)]
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INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (09) : 782 - 784
[5] Polyoxoanion-supported catalysis:: evidence for a P2W15Nb3O629--supported iridium cyclohexene oxidation catalyst starting from [n-Bu4N]5Na3[(1,5-COD)Ir•P2W15Nb3O62]
Weiner, H
Trovarelli, A
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JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 191 (02) : 253 - 279
[6] CHARACTERIZATION OF LARGE, POLYANIONIC INORGANIC MOLECULES - FAST-ATOM-BOMBARDMENT MASS-SPECTROMETRY OF P2W15NB3O62(9)- AND OF THE SUPPORTED ORGANOMETALLIC CATALYST PRECURSOR (1,5-COD)IR-CENTER-DOT P2W15NB3O62(8)-
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INORGANIC CHEMISTRY, 1993, 32 (26) : 6034 - 6039
[7] FORMATION OF PT(CH3)(CF3) (DIOLEFIN) FROM PT(CH3)2(DIOLEFIN) AND CF3I (DIOLEFIN = NBD, NORBORNADIENE, OR COD, 1,5-CYCLOOCTADIENE) - THE CRYSTAL-STRUCTURES OF (ETA-4-NORBORNADIENE)(METHYL)(TRIFLUOROMETHYL)-PLATINUM(II) AND (ETA-4-NORBORNADIENE)BIS(TRIFLUOROMETHYL)PLATINUM(II)
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[8] POLYOXOANIONS AS SOLUBLE METAL-OXIDE ANALOGS .5. SYNTHESIS AND CHARACTERIZATION OF POLYOXOANION-SUPPORTED, ATOMICALLY DISPERSED IRIDIUM(I), (1,5-COD)IR.P2W15NB3O62(8-)
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INORGANIC CHEMISTRY, 1990, 29 (10) : 1784 - 1787
[9] TRISUBSTITUTED HETEROPOLYTUNGSTATES AS SOLUBLE METAL-OXIDE ANALOGS - ISOLATION AND CHARACTERIZATION OF [(C(5)ME(5))RH-CENTER-DOT-P2W15NB3O62](7-) AND [(C6H6)RU-CENTER-DOT-P2W15NB3O62](7-), INCLUDING THE FIRST CRYSTAL-STRUCTURE OF A DAWSON-TYPE POLYOXOANION-SUPPORTED ORGANOMETALLIC COMPLEX
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INORGANIC CHEMISTRY, 1995, 34 (04) : 767 - 777
[10] Stabilization of the (η4-COD)Pt-fragment (COD = η2,η2-cyclo-octa-1,5-diene) by a bistriazenide:: Synthesis and X-ray structural characterization of [(η4-COD)Pt(NNN-Ph)2C6H4], a neutral 1,2-bis(phenyltriazenido)benzene complex of platinum(II)
Hörner, M
de Oliveira, GM
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Filgueiras, CAL
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JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (1-2) : 251 - 254

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