Catalytic performance of nanostructured Pt/ZSM-5 catalysts synthesized by extended Charnell's method in hydroisomerization of n-pentane

被引:10
|
作者
Aghdam, N. Charchi [1 ,2 ]
Ejtemaei, M. [1 ,2 ]
Sharafi, S. M. [1 ,2 ]
Babaluo, A. A. [1 ,2 ]
Tavakoli, A. [1 ,2 ]
Bayati, B. [2 ,3 ]
机构
[1] Sahand Univ Technol, Chem Engn Dept, POB 51335-1996, Tabriz, Iran
[2] Sahand Univ Technol, NMRC, POB 51335-1996, Tabriz, Iran
[3] Ilam Univ, Dept Chem Engn, Ilam, Iran
关键词
ZSM-5; Extended Charnell's method; Trien; Nanocatalyst; Hydroisomerization; ZSM-5; ZEOLITE; ISOMERIZATION; DESILICATION; HEXANE; MESOPOROSITY; PLATINUM; ACIDITY; BUTANE; HBEA;
D O I
10.1016/j.poly.2019.01.056
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Na-ZSM-5 zeolite, synthesized by extended Charnell's method was used to prepare Pt/ZSM-5 catalyst for n-pentane hydroisomerization. The influence of ion exchange, alkaline treatment and method of platinum incorporation on the Na-ZSM-5 zeolite was investigated. It was found that the presence of Trien affected the physicochemical properties of the synthesized catalyst. The synthesized catalysts showed high performance so that the sample prepared in rotating mode at 24 h and Pt loaded via impregnation showed conversion and selectivity about 75 and 97%, respectively. Also, a maximum yield for this catalyst was achieved at 250 degrees C. (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页码:155 / 164
页数:10
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