Expanding the Carbene C-H Insertion Toolbox

被引：6
|
作者：
Morton, Daniel [1 ]
Blakey, Simon B. [1 ]
机构：
[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA
来源：
CHEMCATCHEM | 2015年 / 7卷 / 04期
基金：
美国国家科学基金会;
关键词：
carbenes; catalysis; CH functionalization; rhodium; ruthenium; DIAZO-COMPOUNDS; IN-SITU;
D O I：
10.1002/cctc.201402945
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A Bigger toolbox: Two recent discoveries demonstrate significant advances in the controlled generation and C-H insertion chemistry of the previously inaccessible donor-donor and alkyl-alkyl classes of metallocarbenes. These discoveries lay the groundwork for broad reaction development with these versatile reactive species. EDG=Electron-donating group; EWG=Electron-withdrawing group; M=Transition metal. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：577 / 578
页数：2
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