Determination of Abraham model solute descriptors for three dichloronitrobenzenes from measured solubilities in organic solvents

被引：20

作者：

Brumfield, Michela ^{[1
]}

Wadawadigi, Akash ^{[1
]}

Kuprasertkul, Napasorn ^{[1
]}

Mehta, Sumedha ^{[1
]}

Stephens, Timothy W. ^{[1
]}

Barrera, Maribel ^{[1
]}

De La Rosa, Jennifer ^{[1
]}

Kennemer, Logan ^{[1
]}

Meza, Jocelin ^{[1
]}

Acree, William E., Jr. ^{[1
]}

Abraham, Michael H. ^{[2
]}

机构：

[1] Univ N Texas, Dept Chem, Denton, TX 76203 USA

[2] UCL, Dept Chem, London WC1H OAJ, England

来源：

PHYSICS AND CHEMISTRY OF LIQUIDS | 2015年 / 53卷 / 02期

关键词：

organic solvents; Abraham model; solute descriptors; solubility; dichloronitrobenzenes; SOLVATION PARAMETER MODEL; ENERGY RELATIONSHIP CORRELATION; CHEMICAL TOXICITY CORRELATIONS; ALGAE SCENEDESMUS-OBLIQUUS; CHROMATOGRAPHIC MEASUREMENTS; SUBSTITUTED BENZENES; WATER; SYSTEMS; PARTITION; ENTHALPY;

D O I：

10.1080/00319104.2014.972555

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mole fraction solubilities are reported for 1,4-dichloro-2-nitrobenzene dissolved in 24 organic solvents of varying polarity and hydrogen-bonding character. The experimental data are used to calculate Abraham solute descriptors. The calculated solute descriptors describe the experimental data to within an overall average standard deviation of 0.081 log units. Also reported in the manuscript are Abraham model solute descriptors for both 3,4-dichloro-1-nitrobenzene and 2,3-dichloro-1-nitrobenzene based on published literature data.

引用

页码：163 / 173

页数：11

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