Relationship between metal-metal bond length and internal rotation in diruthenium tetracarboxylate paddlewheel complexes

被引：11
|
作者：
Gracia, Raquel [1 ]
Adams, Harry [1 ]
Patmore, Nathan J. [1 ]
机构：
[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England
来源：
DALTON TRANSACTIONS | 2009年 / 02期
关键词：
MOLECULE; ORDERS; SERIES; WATER;
D O I：
10.1039/b820287g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Ru-Ru bond length for Ru-2(II,III) and Ru-2(II,II) paddlewheel complexes containing the bulky carboxylate ligand 2,4,6-triisopropylbenzoate was found to decrease despite a reduction in Ru-Ru bond order, due to increased internal rotation.
引用
收藏
页码：259 / 261
页数：3
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