Supramolecular chemistry: Functionalization of [60]fullerene with vaporous reagents via its calix[8]arene complex

被引：0
|
作者：
Fang, PF
Chen, YY [1 ]
Lu, XR
Zhu, L
机构：
[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
[2] Wuhan Univ, Dept Anal & Measurement, Wuhan 430072, Peoples R China
来源：
SYNTHETIC COMMUNICATIONS | 1999年 / 29卷 / 20期
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D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new approach to functionalization of fullerene is developed: treating [60]fullerene p-tert-butyl calix[8]arene Complex with vaporous reagents, such as chlorine, vaporous bromine or vaporous amines. A dramatic reaction acceleration was observed and derivatives with smaller substitution degree were obtained in the reaction in comparison with the reaction of [60]fullerene itself The influences of temperature and gas flow rate were investigated.
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页码：3547 / 3554
页数：8
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