Thermodynamic modeling of the CaO-SiO2-ZrO2 system coupled with key phase diagram experiments

被引：17

作者：

Kwon, Sun Yong ^{[1
]}

Kim, Wan-Yi ^{[2
]}

Hudon, Pierre ^{[1
]}

Jung, In-Ho ^{[1
]}

机构：

[1] McGill Univ, Dept Min & Mat Engn, 3610 Univ St, Montreal, PQ H3A 0C5, Canada

[2] Posco Steelmaking Lab, Pohang, South Korea

来源：

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 2017年 / 37卷 / 03期

基金：

加拿大自然科学与工程研究理事会;

关键词：

CaO-SiO2-ZrO2; Thermodynamic modeling; Phase diagram; Gibbs energy; CALCIUM ZIRCONIUM SILICATE; QUASI-CHEMICAL MODEL; CELLS;

D O I：

10.1016/j.jeurceramsoc.2016.10.011

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Thermodynamic modeling coupled with key phase diagram experiments of the ternary CaO-SiO2-ZrO2 system was carried out. The isothermal phase diagram of the CaO-SiO2-ZrO2 system at 1873 K was established by using a classical phase equilibration and quenching technique followed by EPMA phase analysis. The Gibbs energy of each phase was optimized through critical evaluation of all available thermodynamic properties and phase diagram data in literature with new experimental data. The discrepancies between experimental phase diagram data and possible errors in the existing thermodynamic data were resolved in this study. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：1095 / 1104

页数：10

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