Formation constants of polynuclear aromatic compounds and beta-cyclodextrin inclusion complexes in beta-cyclodextrin modified mobile phase high performance liquid chromatography system

被引：21
|
作者：
Tang, JJ [1 ]
Love, LJC [1 ]
机构：
[1] SETON HALL UNIV, DEPT CHEM, S ORANGE, NJ 07079 USA
来源：
ANALYTICA CHIMICA ACTA | 1997年 / 344卷 / 1-2期
关键词：
liquid chromatography; cyclodextrins; inclusion complexes;
D O I：
10.1016/S0003-2670(96)00577-6
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The effects of molecular size and shape upon the formation of inclusion complexes of beta-cyclodextrin (beta-CD) and polynuclear aromatic compounds in beta-CD modified mobile phase high performance liquid chromatography (HPLC) system were studied. A correlation was established between the molecular size and shape of the probe compounds and the formation constants of the inclusion complexes. The formation constants were then used to support the elucidation of inclusion complexes formation based on the structural properties.
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页码：137 / 143
页数：7
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