Self-assembly and x-ray structure of a ten-component, three-dimensional metallosupramolecular cage

被引：176
|
作者：
Hartshorn, CM [1 ]
Steel, PJ [1 ]
机构：
[1] UNIV CANTERBURY,DEPT CHEM,CHRISTCHURCH 1,NEW ZEALAND
来源：
CHEMICAL COMMUNICATIONS | 1997年 / 06期
关键词：
D O I：
10.1039/a608081b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of 1,3,5-tris(pyrazol-1-ylmethyl)-2,4,6-triethylbenzene 7 with palladium chloride results in the self-assembly of a three-dimensional cage; an X-ray crystal structure determination shows that the cage is comprised of an octahedral arrangement of six palladium atoms bridged by a tetrahedral network of four molecules of the ligand and contains a (disordered) guest molecule of dimethyl sulfoxide.
引用
收藏
页码：541 / 542
页数：2
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