New research areas inspired by sustainable development

被引:5
|
作者
Da Silva, Eric [1 ]
Dayoub, Wissam [1 ]
Duguet, Nicolas [1 ]
Metay, Estelle [1 ]
Popowycz, Florence [2 ]
Lemaire, Marc [1 ]
机构
[1] Univ Lyon 1, ICBMS CNRS UMR 5246, Inst Chim & Biochim Mol & Supramol, Lab Catalyse Synth & Environm, F-69622 Villeurbanne, France
[2] Inst Natl Sci Appl INSA Lyon, ICBMS CNRS UMR 5246, Lab Chim Organ & Bioorgan, F-69621 Villeurbanne, France
关键词
Green chemistry; Polyhydrosiloxanes; Glycerol; ScCO2; C(sp(2))-H activation; PALLADIUM-CATALYZED ARYLATION; CARBON BOND FORMATION; SELECTIVE SYNTHESIS; PROPYLENE-GLYCOL; REDUCTION; DERIVATIVES; EXTENSION; GLYCEROL; DIOXIDE; HALIDES;
D O I
10.1016/j.crci.2012.12.019
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
More than 20 years after its birth, green chemistry has definitely entered its golden age. In this account, we highlight some of our progress made over the last 10 years towards the development of green methodologies. We investigated various aspects of green chemistry such as new reagents, catalysts, transformations and solvents and also the utilization of renewable resources. We report herein four mature projects illustrating our efforts in these fields: (1) polyhydrosiloxanes as new reducing agents; (2) glycerol as a new platform for amphiphilic molecules; (3) water, room-temperature ionic liquids and supercritical carbon dioxide as new solvents and (4) C(sp(2))-H activation as new C-C bond formation methodology. An overview of each project is given and the potential applications are discussed. (C) 2013 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.
引用
收藏
页码:343 / 349
页数:7
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