Synthesis of heteroleptic pyrrolide/bipyridyl complexes of ruthenium(II)

被引：14
|
作者：
Lundrigan, Travis [1 ]
Jackson, Carla L. M. [1 ]
Uddin, Md Imam [1 ]
Tucker, Lloyd A. [1 ]
Ali, Adeeb Al-Sheikh [1 ,2 ]
Linden, Anthony [3 ]
Cameron, T. Stanley [1 ]
Thompson, Alison [1 ]
机构：
[1] Dalhousie Univ, Dept Chem, Halifax, NS B3H 4R2, Canada
[2] Taibah Univ, Dept Chem, Al Munawarrah, Saudi Arabia
[3] Univ Zurich, Inst Organ Chem, CH-8057 Zurich, Switzerland
来源：
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 2012年 / 90卷 / 08期
基金：
加拿大自然科学与工程研究理事会;
关键词：
ruthenium complexation; formyl pyrrole; keto pyrrole; chelation; PYRROLYL LIGANDS; CHEMISTRY; SUBSTITUTION; REACTIVITY;
D O I：
10.1139/V2012-045
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis and characterization of the first heteroleptic pyrrolide/2,2'-bipyridyl complexes of ruthenium(II) are reported. Pyrroles substituted at the 2-position with X = O functionality react with Ru(bipy)(2)Cl-2.2H(2)O to form complexes in which the pyrrolide ligands chelate to Ru(II). The library of pyrroles includes 2-formyl, 2-keto, 2-carboxylato, 2-sulfinyl, and 2-sulfonyl derivatives.
引用
收藏
页码：693 / 700
页数：8
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